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A Tris-Chelate Nickel Complex of Formylhydrazine: Synthesis and Crystal Structure

  • A. A. Zabolotnyi,
  • O. P. Demidov,
  • S. B. Zaichenko,
  • A. V. Bicherov,
  • N. V. Ter-Oganessian

摘要

Abstract

The Ni(FH)3Cl2·H2O complex is prepared by the in situ reaction of formic acid, hydrazine hydrate, and nickel(II) chloride. It is structurally characterized as a tris-chelated complex cation containing chloride anions as counterions and crystallizing in the P21/c centrosymmetric monoclinic space group.