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<p>Generalized Rosenfeld–Tarazona scaling predicts the power-law dependence of the excess heat capacity of simple liquids on temperature. The two-phase model treats a liquid as a superposition of gas- and solid-like components whose relative abundance is quantified by a liquid rigidity parameter. We demonstrate here that the generalized Rosenfeld–Tarazona scaling emerges naturally in the two-phase model from the scale invariance of the liquid rigidity parameter.</p>

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Heat Capacity of Dense Liquids: A Link Between Two-Phase Model and Melting Temperature Scaling

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年8月8日

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  • S. A. Khrapak,
  • A. G. Khrapak

摘要

Generalized Rosenfeld–Tarazona scaling predicts the power-law dependence of the excess heat capacity of simple liquids on temperature. The two-phase model treats a liquid as a superposition of gas- and solid-like components whose relative abundance is quantified by a liquid rigidity parameter. We demonstrate here that the generalized Rosenfeld–Tarazona scaling emerges naturally in the two-phase model from the scale invariance of the liquid rigidity parameter.