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<p>Analysis of the nuclear magnetic resonance linewidth and spin-lattice relaxation rate of <sup>175</sup>Lu in LuB<sub>12</sub> assumes a structural transition at <i>T</i>*~150&#xa0;K into a state with a long-range ferrodistortive order of lattice distortions caused by the cooperative Jahn–Teller effect. The reported experimental facts imply this transition to be characteristic of other rare-earth dodecaborides.</p>

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Structural Transition in Dodecaborides According to NMR in LuB12

  • 期刊论文

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  • 发表日期：

    2025年5月1日

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  • O. M. Vyaselev,
  • A. A. Gippius,
  • N. E. Sluchanko

摘要

Analysis of the nuclear magnetic resonance linewidth and spin-lattice relaxation rate of 175Lu in LuB12 assumes a structural transition at T*~150 K into a state with a long-range ferrodistortive order of lattice distortions caused by the cooperative Jahn–Teller effect. The reported experimental facts imply this transition to be characteristic of other rare-earth dodecaborides.