Abstract <p>The paper presents the results of studies of the structural-phase state and chemical composition of a membrane made of Pd–40 wt % Cu (Pd–52.8 at % Cu) alloy after its operation in an experimental hydrogen separation reactor for 20 hours at a temperature of 473–523 K. The methods of scanning and transmission electron microscopy, X-ray phase analysis and energy-dispersive spectroscopy A study of the evolution of the structural-phase state of the alloy under study was conducted with an analysis of the mechanisms of the observed processes.</p>

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Patterns of Structural and Phase Transformations in Membranes Made of Pd–40% Cu Alloy under Hydrogen Separation Conditions

  • S. S. Manokhin,
  • V. N. Maksimenko,
  • A. Yu. Tokmacheva-Kolobova,
  • A. E. Ligachev,
  • I. V. Sedov,
  • Yu. R. Kolobov

摘要

Abstract

The paper presents the results of studies of the structural-phase state and chemical composition of a membrane made of Pd–40 wt % Cu (Pd–52.8 at % Cu) alloy after its operation in an experimental hydrogen separation reactor for 20 hours at a temperature of 473–523 K. The methods of scanning and transmission electron microscopy, X-ray phase analysis and energy-dispersive spectroscopy A study of the evolution of the structural-phase state of the alloy under study was conducted with an analysis of the mechanisms of the observed processes.