Phase Equilibria in the LiF–KCl–KBr–LiKCrO₄ Stable Tetrahedron of the Quinary Reciprocal System Li⁺,K⁺||F^–,Cl^–,Br^–,\({\text{CrO}}_{4}^{{2 - }}\)

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发表日期：

2024年7月1日

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M. A. Sukharenko,
I. S. Portnova,
A. S. Egorova,
I. K. Garkushin,
I. M. Kondratyuk

摘要

Abstract—

We have studied the LiF–KCl–KBr–LiKCrO₄ stable tetrahedron of the quinary reciprocal system Li⁺,K⁺||F^–,Cl^–,Br^–, \({\text{CrO}}_{4}^{{2 - }}\) . According to experimental data obtained by differential thermal analysis, three solid phases crystallize in the stable tetrahedron: LiF, LiKCrO₄, and a continuous series of KCl_xBr_1–x solid solutions. The solid solutions are stable, and there are no invariant equilibrium points.

Phase Equilibria in the LiF–KCl–KBr–LiKCrO4 Stable Tetrahedron of the Quinary Reciprocal System Li+,K+||F–,Cl–,Br–,\({\text{CrO}}_{4}^{{2 - }}\)

摘要

Phase Equilibria in the LiF–KCl–KBr–LiKCrO₄ Stable Tetrahedron of the Quinary Reciprocal System Li⁺,K⁺||F^–,Cl^–,Br^–,\({\text{CrO}}_{4}^{{2 - }}\)