Abstract <p>The oxidation of propane–butane and propane–methane mixtures in dielectric-barrier discharge (DBD) plasma to the corresponding hydroxyl and carbonyl compounds has been studied. As a result, both compounds undergo conversion, but the hydrocarbon with a higher molecular weight has a higher oxidation rate. The main pathways of <i>n</i>-butane molecule dissociation under the action of DBD plasma are proposed, based on a comparative analysis of experimental data, calculations of electron energy losses, and fragmentation variants of electronically excited ethane and propane molecules.</p>

错误:搜索内容不能为空,请输入英文关键词
错误:关键词超出字数限制,请精简
高级检索

Oxidation of Gaseous Alkane Mixtures in Dielectric Barrier Discharge

  • A. Yu. Ryabov,
  • S. V. Kudryashov

摘要

Abstract

The oxidation of propane–butane and propane–methane mixtures in dielectric-barrier discharge (DBD) plasma to the corresponding hydroxyl and carbonyl compounds has been studied. As a result, both compounds undergo conversion, but the hydrocarbon with a higher molecular weight has a higher oxidation rate. The main pathways of n-butane molecule dissociation under the action of DBD plasma are proposed, based on a comparative analysis of experimental data, calculations of electron energy losses, and fragmentation variants of electronically excited ethane and propane molecules.