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Pump–Probe Spectroscopic Study of Charge Carrier Transport Processes in Films of CsPbBr3 Perovskite Colloidal Quantum Dots

  • A. A. Galushko,
  • G. A. Lochin,
  • D. N. Pevtsov,
  • A. V. Aibush,
  • F. E. Gostev,
  • I. V. Shelaev,
  • V. A. Nadtochenko,
  • S. B. Brichkin,
  • V. F. Razumov

摘要

Abstract

Colloidal quantum dots of CsPbBr3 perovskites have been synthesized. The average size and polydispersity of nanocrystals were determined to be 8.3 nm and 16%, respectively. Thin films were made based on the obtained nanocrystals using drop-casting and spin-coating methods. The charge carrier transport process was studied using the technique of femtosecond laser pump–probe spectroscopy. An interpretation of the shift in the bleaching peak as a function of time is proposed. The mobility of charge carriers in films has been estimated using the Einstein–Smoluchowski equation.