<p>Wastewater treatment plants (WWTPs) are major sources of gaseous nitrogen (N) emissions. The nitrous oxide (N<sub>2</sub>O) emissions have been extensively studied, however, how ammonia (NH<sub>3</sub>) emissions contribute to N<sub>2</sub>O emissions, soil acidification and particulate matter (PM<sub>2.5</sub>) formation, have been largely overlooked. This study quantified NH<sub>3</sub> and N<sub>2</sub>O emissions from a sludge drying pan (SDP), using inverse-dispersion modelling coupled with open-path Fourier infrared spectroscopic techniques. Here we show low N<sub>2</sub>O emissions (&lt;0.001 g m<sup>−2</sup> h<sup>−1</sup>) and mean NH<sub>3</sub> emissions that are much higher in summer (0.293 g m<sup>−2</sup> h<sup>−1</sup>) than in winter (0.060 g m<sup>−2</sup> h<sup>−1</sup>). A mechanistic process model, correlating NH<sub>3</sub> emissions with wind speed and temperature, predicts total NH<sub>3</sub> emissions over the SDP cycle (634 days) at 43 t of NH<sub>3</sub>‒N. This represents 30% of total N in the SDP and 6–9% of total N in the WWTPs influent. This study highlights that the use of SDPs by WWTPs is a substantial NH<sub>3</sub> emission source, offering new perspectives for mitigating global N emissions.</p>

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Substantial ammonia emissions from sludge drying pans in wastewater treatment plants

  • Mei Bai,
  • Zhiyao Wang,
  • Dilini Seneviratne,
  • James Lloyd,
  • Pieter De Jong,
  • Liu Ye,
  • Deli Chen

摘要

Wastewater treatment plants (WWTPs) are major sources of gaseous nitrogen (N) emissions. The nitrous oxide (N2O) emissions have been extensively studied, however, how ammonia (NH3) emissions contribute to N2O emissions, soil acidification and particulate matter (PM2.5) formation, have been largely overlooked. This study quantified NH3 and N2O emissions from a sludge drying pan (SDP), using inverse-dispersion modelling coupled with open-path Fourier infrared spectroscopic techniques. Here we show low N2O emissions (<0.001 g m−2 h−1) and mean NH3 emissions that are much higher in summer (0.293 g m−2 h−1) than in winter (0.060 g m−2 h−1). A mechanistic process model, correlating NH3 emissions with wind speed and temperature, predicts total NH3 emissions over the SDP cycle (634 days) at 43 t of NH3‒N. This represents 30% of total N in the SDP and 6–9% of total N in the WWTPs influent. This study highlights that the use of SDPs by WWTPs is a substantial NH3 emission source, offering new perspectives for mitigating global N emissions.