Scholarlink

<p>Few chemical methods controllably generate <i>sp</i><sup>3</sup> defects on single-walled carbon nanotubes, and fewer still create quantum wells that localize excitons and enhance near-infrared emission. Here we describe an aqueous, nanotube-catalysed Fenton reaction that enables the conjugation of an extensive range of small molecules lacking traditional single-walled carbon nanotube conjugation handles, generating quantum well defects with tunable electro-optical properties. We demonstrate the attachment of over 150 unique small molecules, including alcohols, amines, carbonyls, acrylates, amino acids and peptides. The resulting optical properties are governed by the electronic structure of the attached group, which determines the relative configuration of defects (<i>ortho</i> or <i>para</i>) within the graphitic lattice. Time-dependent density functional theory calculations confirm the assignment of the observed emission peaks to specific defect configurations. These molecularly driven effects enable precise control over the optical properties of the nanotubes, broadening the design space of rationally engineered quantum well-bearing nanomaterials.</p><p></p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Handle-free attachment of small molecules on single-walled carbon nanotubes

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2026年4月21日

查看全文
  • Stanislav S. Piletsky,
  • Erin E. Keblish,
  • Alec R. Goffin,
  • Xiaojia Jin,
  • In-Jun Hwang,
  • August Amb,
  • Dmitri Kilin,
  • Svetlana Kilina,
  • Ming Zheng,
  • Mijin Kim,
  • Daniel A. Heller

摘要

Few chemical methods controllably generate sp3 defects on single-walled carbon nanotubes, and fewer still create quantum wells that localize excitons and enhance near-infrared emission. Here we describe an aqueous, nanotube-catalysed Fenton reaction that enables the conjugation of an extensive range of small molecules lacking traditional single-walled carbon nanotube conjugation handles, generating quantum well defects with tunable electro-optical properties. We demonstrate the attachment of over 150 unique small molecules, including alcohols, amines, carbonyls, acrylates, amino acids and peptides. The resulting optical properties are governed by the electronic structure of the attached group, which determines the relative configuration of defects (ortho or para) within the graphitic lattice. Time-dependent density functional theory calculations confirm the assignment of the observed emission peaks to specific defect configurations. These molecularly driven effects enable precise control over the optical properties of the nanotubes, broadening the design space of rationally engineered quantum well-bearing nanomaterials.