Giant impacts trigger crustal recycling as witnessed by sulfur isotopes in lunar basalts
摘要
Crustal recycling, a fundamental process promoting planetary differentiation, is conventionally attributed to plate tectonics on Earth. However, the mechanisms driving this process in tectonically stagnant regimes remain ambiguous. The heavy sulfur isotope (δ34S = 2.0–2.4‰) composition of troilites in the newly-discovered 4.2 Ga high-Al basalt from the South Pole–Aitken (SPA) basin indicates the incorporation of surficial degassed 34S-enriched crustal materials into the mantle. Numerical simulations of the SPA-forming impact and the induced mantle convection show that uplifted molten crustal materials are exposed to vacuum for about one hour, leading to degassing and enrichment of 34S, then transported to depths greater than 200 km to provide a hybrid mantle source for high-Al basaltic magmatism. Our integrated petrological geochemical numerical study provides the mechanistic validation of impact-driven crustal recycling on the Moon, fundamentally advancing our capacity to decode early crust–mantle evolution in terrestrial bodies within the inner Solar System.