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The pseudochiral Fermi surface of α-RuI3

  • Alex Louat,
  • Matthew D. Watson,
  • Timur K. Kim,
  • Danrui Ni,
  • Robert J. Cava,
  • Cephise Cacho

摘要

In continuation of research into RuCl3 and RuBr3 as potential quantum spin liquids, a phase with unique magnetic order characterised by long-range quantum entanglement and fractionalised excitations, the compound RuI3 has been recently synthesised. Here, we show RuI3 is a moderately correlated metal with two bands crossing the Fermi level, implying the absence of any quantum spin liquids phase. We find that the Fermi surface as measured or calculated for a 2D (kx, ky) slice at any kz lacks mirror symmetry, i.e. is pseudochiral. We link this phenomenon to the ABC stacking in the R \(\bar{3}\) 3 ¯ space group of α-RuI3, which is achiral but lacks any mirror or glide symmetries. We further provide a formal framework for understanding when such a pseudochiral electronic structure may be observed.