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<p>The use of weak, inexpensive bases in the assembly of late-transition metal NHC complexes represents a most promising synthetic strategy. We now disclose the use of gaseous and aqueous ammonia as bases for the continuous-flow synthesis of these complexes with Au, Pd, and Cu metal centers. The fully homogeneous system enables reactions to proceed under milder, faster, and more concentrated conditions than state-of-the-art methods.</p><p></p>

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Ammonia as a weak base for continuous-flow synthesis of Au, Pd, and Cu-NHC heteroleptic chloro complexes

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年12月29日

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  • Riku Saito,
  • Andreas Simoens,
  • Celle Vandersteen,
  • Christian V. Stevens,
  • Steven P. Nolan

摘要

The use of weak, inexpensive bases in the assembly of late-transition metal NHC complexes represents a most promising synthetic strategy. We now disclose the use of gaseous and aqueous ammonia as bases for the continuous-flow synthesis of these complexes with Au, Pd, and Cu metal centers. The fully homogeneous system enables reactions to proceed under milder, faster, and more concentrated conditions than state-of-the-art methods.