<p>The electrocatalytic reduction of nitrate (NO<sub>3</sub><sup>−</sup>) and nitrite (NO<sub>2</sub><sup>−</sup>) to ammonia (NH<sub>3</sub>), herein NO<sub>x</sub>RA, has recently attracted much attention in the broader field of NO<sub>x</sub><sup>−</sup> electroreduction (NO<sub>x</sub>ER), particularly in catalyst development. Many promising NO<sub>x</sub>RA catalysts have been reported, though translation of these catalysts into devices and processes remains limited. This appears to be partially correlated to the catalyst testing conditions employed. Herein, the electrolytes reported in 411 papers published from January 2023 to June 2024 were compared to the compositions of NO<sub>x</sub><sup>−</sup>-laden water sources. Approximately 60% of these papers employed pH and NO<sub>3</sub><sup>−</sup>/NO<sub>2</sub><sup>−</sup> concentration ([NO<sub>x</sub><sup>−</sup>]) combinations matching water sources with very limited potential as NO<sub>x</sub>RA feedstocks. This suggests a large proportion of NO<sub>x</sub>RA catalyst research targets scenarios where NO<sub>x</sub>RA will be inherently ineffective. To aid translation of research to application, this perspective suggests criteria by which suitable NO<sub>x</sub>RA, and more broadly, NO<sub>x</sub>ER, feedstocks might be identified, to mimic relevant conditions for catalyst testing through: (i) appropriate matching of pH and [NO<sub>x</sub><sup>−</sup>], (ii) explicit selection of the substrate (i.e. NO<sub>3</sub><sup>−</sup> and/or NO<sub>2</sub><sup>−</sup>), and (iii) inclusion of other expected species. Using this approach, recommended conditions are provided for two examples of viable NO<sub>x</sub><sup>−</sup>-laden feedstocks.</p><p></p>

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A systematic critique of electrolyte choices in recent literature on the electrochemical reduction of NOx

  • Alexander Marcus Leon Frisina,
  • Christopher Barnett,
  • Alexander Kah Liem Yuen,
  • Anthony Frederick Masters,
  • Thomas Maschmeyer

摘要

The electrocatalytic reduction of nitrate (NO3) and nitrite (NO2) to ammonia (NH3), herein NOxRA, has recently attracted much attention in the broader field of NOx electroreduction (NOxER), particularly in catalyst development. Many promising NOxRA catalysts have been reported, though translation of these catalysts into devices and processes remains limited. This appears to be partially correlated to the catalyst testing conditions employed. Herein, the electrolytes reported in 411 papers published from January 2023 to June 2024 were compared to the compositions of NOx-laden water sources. Approximately 60% of these papers employed pH and NO3/NO2 concentration ([NOx]) combinations matching water sources with very limited potential as NOxRA feedstocks. This suggests a large proportion of NOxRA catalyst research targets scenarios where NOxRA will be inherently ineffective. To aid translation of research to application, this perspective suggests criteria by which suitable NOxRA, and more broadly, NOxER, feedstocks might be identified, to mimic relevant conditions for catalyst testing through: (i) appropriate matching of pH and [NOx], (ii) explicit selection of the substrate (i.e. NO3 and/or NO2), and (iii) inclusion of other expected species. Using this approach, recommended conditions are provided for two examples of viable NOx-laden feedstocks.