<p>Reconfigurable devices that can switch functionalities could be used to overcome the limitations of miniaturized metal–oxide–semiconductor field-effect transistors. Conventional approaches typically involve the partial electrostatic modulation of two-dimensional semiconductors and use partial floating gates or dual-gate structures. Reconfigurable devices based on vertical van der Waals heterostructures have much simpler device structures, but lack a scalable assembly method. Here, we report a scalable reconfigurable device based on solution-processed van der Waals heterostructures. We vertically assemble thin films of sub-stoichiometric zirconium oxide (ZrO<sub>2-<i>x</i></sub>) as a dielectric and molybdenum disulfide (MoS<sub>2</sub>) as a semiconductor layer. The ZrO<sub>2-<i>x</i></sub>/MoS<sub>2</sub> heterostructure provides simultaneous global and local gating within a single-gate transistor configuration, modulating the spatial electric field across the device in a reconfigurable manner. Under global gating conditions, the devices function as uniform field-effect transistors with an average field-effect mobility of 10 cm<sup>2</sup> V<sup>−1</sup> s<sup>−1</sup> and current on/off ratio of up to 10<sup>6</sup>. Under local gating conditions, the devices function as diodes, exhibiting a current rectification ratio of around 7 × 10<sup>4</sup>. By harnessing the reconfigurable characteristics, we achieve adjustable temporal photoresponse dynamics with a photoresponsivity of around 10<sup>5</sup> A W<sup>−1</sup>, high spatial uniformity and multi-spectral photodetection. We also use the approach to create a large-area reconfigurable optoelectronics array.</p>

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Sub-stoichiometric zirconium oxide as a solution-processed dielectric for reconfigurable electronics

  • Kangsan Kim,
  • Jihyun Kim,
  • Myeongjin Jung,
  • In Soo Kim,
  • Byoung-Soo Yu,
  • Sang Min Won,
  • Donghee Son,
  • Heng Li,
  • Zdeněk Sofer,
  • Do Kyung Hwang,
  • Deep Jariwala,
  • Joohoon Kang

摘要

Reconfigurable devices that can switch functionalities could be used to overcome the limitations of miniaturized metal–oxide–semiconductor field-effect transistors. Conventional approaches typically involve the partial electrostatic modulation of two-dimensional semiconductors and use partial floating gates or dual-gate structures. Reconfigurable devices based on vertical van der Waals heterostructures have much simpler device structures, but lack a scalable assembly method. Here, we report a scalable reconfigurable device based on solution-processed van der Waals heterostructures. We vertically assemble thin films of sub-stoichiometric zirconium oxide (ZrO2-x) as a dielectric and molybdenum disulfide (MoS2) as a semiconductor layer. The ZrO2-x/MoS2 heterostructure provides simultaneous global and local gating within a single-gate transistor configuration, modulating the spatial electric field across the device in a reconfigurable manner. Under global gating conditions, the devices function as uniform field-effect transistors with an average field-effect mobility of 10 cm2 V−1 s−1 and current on/off ratio of up to 106. Under local gating conditions, the devices function as diodes, exhibiting a current rectification ratio of around 7 × 104. By harnessing the reconfigurable characteristics, we achieve adjustable temporal photoresponse dynamics with a photoresponsivity of around 105 A W−1, high spatial uniformity and multi-spectral photodetection. We also use the approach to create a large-area reconfigurable optoelectronics array.