<p>Open-path sensors are critical for expanding methane (CH<sub>4</sub>) eddy covariance flux observations in power-constrained environments but are traditionally hindered by density and spectroscopic artifacts that reduce measurement confidence. This study introduces the HT8600P, an open-path analyzer enabling a novel pseudo dry mixing ratio (<InlineEquation ID="IEq1"><EquationSource Format="TEX">\({\chi }_{p})\)</EquationSource><EquationSource Format="MATHML"><math><mrow><msub><mrow><mi>χ</mi></mrow><mrow><mi>p</mi></mrow></msub><mo>)</mo></mrow></math></EquationSource></InlineEquation> method. In a zero-flux experiment, this method yielded near-zero fluxes with a random error of 0.057 mg·m<sup>−2</sup>·hr<sup>−1</sup> (<InlineEquation ID="IEq2"><EquationSource Format="TEX">\(1\sigma\)</EquationSource><EquationSource Format="MATHML"><math><mrow><mn>1</mn><mi>σ</mi></mrow></math></EquationSource></InlineEquation>), and a net correction 10 times smaller than a co-located commercial analyzer. We further identify “phantom” errors, artifacts from density and spectroscopic effects, that inflate random error estimates in conventional density-based open-path flux measurements. The <InlineEquation ID="IEq3"><EquationSource Format="TEX">\({\chi }_{p}\)</EquationSource><EquationSource Format="MATHML"><math><msub><mrow><mi>χ</mi></mrow><mrow><mi>p</mi></mrow></msub></math></EquationSource></InlineEquation> method reduced these apparent errors by 60–70%, yielding uncertainty consistent with the empirically determined random error (0.063 mg·m<sup>−2</sup>·hr<sup>−1</sup>) using paired flux measurements. By minimizing corrections and enabling robust uncertainty quantification, the HT8600P and <InlineEquation ID="IEq4"><EquationSource Format="TEX">\({\chi }_{p}\)</EquationSource><EquationSource Format="MATHML"><math><msub><mrow><mi>χ</mi></mrow><mrow><mi>p</mi></mrow></msub></math></EquationSource></InlineEquation> method offer a reliable solution for expanding flux networks in remote regions critical to the global CH<sub>4</sub> budget.</p>

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Towards correction free open-path eddy covariance flux measurements for methane

  • Da Pan,
  • Weihao Shen,
  • Kai Wang,
  • Ting-Jung Lin,
  • Junhui Zeng,
  • Zhimei Liu,
  • Yin Wang

摘要

Open-path sensors are critical for expanding methane (CH4) eddy covariance flux observations in power-constrained environments but are traditionally hindered by density and spectroscopic artifacts that reduce measurement confidence. This study introduces the HT8600P, an open-path analyzer enabling a novel pseudo dry mixing ratio (\({\chi }_{p})\)χp) method. In a zero-flux experiment, this method yielded near-zero fluxes with a random error of 0.057 mg·m−2·hr−1 (\(1\sigma\)1σ), and a net correction 10 times smaller than a co-located commercial analyzer. We further identify “phantom” errors, artifacts from density and spectroscopic effects, that inflate random error estimates in conventional density-based open-path flux measurements. The \({\chi }_{p}\)χp method reduced these apparent errors by 60–70%, yielding uncertainty consistent with the empirically determined random error (0.063 mg·m−2·hr−1) using paired flux measurements. By minimizing corrections and enabling robust uncertainty quantification, the HT8600P and \({\chi }_{p}\)χp method offer a reliable solution for expanding flux networks in remote regions critical to the global CH4 budget.