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<p>Semi-/intermediate volatile organic compounds (S/IVOCs) are important precursors for secondary organic aerosols (SOA) and ozone formation. Vehicle emissions from real-world vehicle fleets are significant anthropogenic source, but their emission profiles and chemical fingerprints remain inadequately characterized. Here, we combined tunnel observation with comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry to investigate vehicular S/IVOCs emissions. We identified 256 vehicle-related compounds with fleet-average emission factors (EFs) of 16.4 ± 12.1 mg·km<sup>−1</sup>·veh<sup>−</sup><sup>1</sup>, comprising 67.2% VOCs, 24.3% IVOCs, and 8.5% SVOCs. VOCs accounted for the majority of ozone formation potential (OFP, 84.8%), whereas VOCs, IVOCs, and SVOCs contributed to SOA formation potential at different times. Importantly, our speciated-based SOA estimation enhanced SOA production estimates by 44.1–76.9% compared to traditional approach. We identified eight potential vehicle-related tracers in S/IVOC range through volcano plots and hierarchical clustering analysis, which could benefit future source apportionments. Our work also offers a novel perspective for screening tracers from various sources beyond vehicle-related emissions.</p>

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Emissions and potential tracer screening of semivolatile/intermediate-volatility organic compounds from urban vehicle fleets

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年5月17日

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  • Yajun Wu,
  • Jianfei Peng,
  • Xiaoguo Wang,
  • Peiji Liu,
  • Yan Liu,
  • Fuyang Zhang,
  • Jinsheng Zhang,
  • Bin Sun,
  • Jingqiao Zhang,
  • Kai Song,
  • Pengfei Song,
  • Lin Wu,
  • Ting Wang,
  • Song Guo,
  • Hongjun Mao

摘要

Semi-/intermediate volatile organic compounds (S/IVOCs) are important precursors for secondary organic aerosols (SOA) and ozone formation. Vehicle emissions from real-world vehicle fleets are significant anthropogenic source, but their emission profiles and chemical fingerprints remain inadequately characterized. Here, we combined tunnel observation with comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry to investigate vehicular S/IVOCs emissions. We identified 256 vehicle-related compounds with fleet-average emission factors (EFs) of 16.4 ± 12.1 mg·km−1·veh−1, comprising 67.2% VOCs, 24.3% IVOCs, and 8.5% SVOCs. VOCs accounted for the majority of ozone formation potential (OFP, 84.8%), whereas VOCs, IVOCs, and SVOCs contributed to SOA formation potential at different times. Importantly, our speciated-based SOA estimation enhanced SOA production estimates by 44.1–76.9% compared to traditional approach. We identified eight potential vehicle-related tracers in S/IVOC range through volcano plots and hierarchical clustering analysis, which could benefit future source apportionments. Our work also offers a novel perspective for screening tracers from various sources beyond vehicle-related emissions.