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<p>Synthesis of sustainable catalytic systems with high efficiency and environmental compatibility remains a critical challenge in modern organic chemistry. Although heterogeneous catalysts offer advantages such as thermal stability, ease of separation and reduced ecological impact, the design of multifunctional platforms that combine structural stability with diverse catalytic features remains a major challenge. In this study, a magnetically recoverable nanocatalyst, diethylenetriamine-functionalized magnetic graphene oxide <b>(</b>Fe<sub>3</sub>O<sub>4</sub>@GO/DETA), is synthesized <i>via</i> a stepwise surface modification strategy. Structural and physicochemical analyses confirmed the successful construction of the composite with preserved crystallinity and magnetic properties. The Fe<sub>3</sub>O<sub>4</sub>@GO/DETA nanocatalyst demonstrated high activity in the Knoevenagel reaction under green conditions and could be magnetically recovered and reused for seven cycles without significant loss of activity. This study demonstrates an effective strategy for developing highly recoverable base-functionalized nanocatalysts for environmentally benign C–C bond-forming processes.</p>

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Diethylenetriamine-functionalized magnetic graphene oxide as a powerful metal-free and recoverable nanocatalyst

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2026年6月25日

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  • Fatemeh Nikrooz,
  • Dawood Elhamifar,
  • Shiva Kargar

摘要

Synthesis of sustainable catalytic systems with high efficiency and environmental compatibility remains a critical challenge in modern organic chemistry. Although heterogeneous catalysts offer advantages such as thermal stability, ease of separation and reduced ecological impact, the design of multifunctional platforms that combine structural stability with diverse catalytic features remains a major challenge. In this study, a magnetically recoverable nanocatalyst, diethylenetriamine-functionalized magnetic graphene oxide (Fe3O4@GO/DETA), is synthesized via a stepwise surface modification strategy. Structural and physicochemical analyses confirmed the successful construction of the composite with preserved crystallinity and magnetic properties. The Fe3O4@GO/DETA nanocatalyst demonstrated high activity in the Knoevenagel reaction under green conditions and could be magnetically recovered and reused for seven cycles without significant loss of activity. This study demonstrates an effective strategy for developing highly recoverable base-functionalized nanocatalysts for environmentally benign C–C bond-forming processes.