Synergistic CuO-CeO2 nanocomposites with narrow band gap for high-performance photocatalysis under solar light irradiation and antibacterial action
摘要
This research introduces a cost-effective method for synthesizing CuO-CeO2 nanocomposites via hydrothermal processing, yielding particles with sizes of 20–30 nm. The nanocomposites exhibit impressive photocatalytic and antimicrobial properties. They demonstrate a direct band gap of 1.66 eV and possess a nano-spherical morphology, as verified by FE-SEM analyses. EDAX analysis reveals the presence of O, Ce, and Cu. Under optimized conditions (pH 7–8, 10 mg of catalyst, and 5 ppm of Orange G dye), the nanocomposites achieve 99.2% dye degradation under solar light, outperforming traditional binary oxides. Kinetic studies reveal a pseudo-first-order reaction, facilitated by the interaction between CuO and CeO2, that enhances charge separation and reactive oxygen species generation. Recyclability tests confirm strong stability, while antimicrobial tests indicate significant efficacy against various strains, including Salmonella typhimurium, Pseudomonas aeruginosa, and Enterobacter aerogenes, particularly at higher CuO ratios. These multifunctional nanocomposites show great potential for sustainable wastewater treatment and effective control of microbial contaminants.