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<p>Copper ferrite (CuFe<sub>2</sub>O<sub>4</sub>) nanoparticles were successfully loaded onto montmorillonite (MMT) to develop a highly active adsorptive material (MMT@CuFe<sub>2</sub>O<sub>4</sub>) capable of removing acid red 18 (AR18) and methylene blue (MB) dyes. Textural, crystalline, and morphological properties were examined by XRD, SEM, FTIR, and BET analyses. A substantial rise in surface area from 12.55 to 43.55&#xa0;m²/g and an increase in total pore volume from 0.0622 to 0.1295&#xa0;cm³/g in MMT@CuFe<sub>2</sub>O<sub>4</sub> relative to MMT demonstrates the successful introduction of mesoporous structures. Adsorption data revealed that the maximum removal efficiencies of MB and AR18 were 74.23% and 88.96%, respectively, under the same conditions of time (180&#xa0;min) and temperature (35&#xa0;°C). The adsorption equilibrium was best described by the Langmuir model, with maximum adsorption capacities (q<sub>max</sub>) of 17.89&#xa0;mg/g for MB and 16.26&#xa0;mg/g for AR18, and high correlation coefficients (R<sup>2</sup> = 0.991 and 0.924). Kinetic data fitted the pseudo-second order model (R² &gt; 0.97), indicating chemisorption as the dominant process, while the Elovich and intra-particle diffusion models further supported multilayer adsorption and intra-pore diffusion. The thermodynamic study demonstrated that adsorption proceeded spontaneously, as shown by the negative ΔG° values (− 3.29 to − 6.75&#xa0;kJ/mol for MB and − 1.27 to − 9.01&#xa0;kJ/mol for AR18), and was endothermic, with respective ΔH° values of 21.37 and 54.18&#xa0;kJ/mol. Among the regeneration systems tested, electro-Fenton exhibited the highest recovery efficiency (75.63% for MB and 82.36% for AR18), whereas thermal regeneration showed the lowest (34.63% and 50.36%, respectively), demonstrating the superior regeneration performance of the EF method and the potential reusability of MMT@CuFe<sub>2</sub>O<sub>4</sub> in practical dye removal applications.</p>

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Assessment of copper ferrite doped montmorillonite for efficient dye removal with insights into operational parameters, adsorption pathways and regeneration capacity

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2026年6月2日

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  • Zahra Sadat Mousavi,
  • Mohammad Darvishmotevalli,
  • Mohammad Reza Zare,
  • Abdolrasoul Rahmani,
  • Davoud Balarak,
  • Nezamaddin Mengelizadeh,
  • Ali Kazemi

摘要

Copper ferrite (CuFe2O4) nanoparticles were successfully loaded onto montmorillonite (MMT) to develop a highly active adsorptive material (MMT@CuFe2O4) capable of removing acid red 18 (AR18) and methylene blue (MB) dyes. Textural, crystalline, and morphological properties were examined by XRD, SEM, FTIR, and BET analyses. A substantial rise in surface area from 12.55 to 43.55 m²/g and an increase in total pore volume from 0.0622 to 0.1295 cm³/g in MMT@CuFe2O4 relative to MMT demonstrates the successful introduction of mesoporous structures. Adsorption data revealed that the maximum removal efficiencies of MB and AR18 were 74.23% and 88.96%, respectively, under the same conditions of time (180 min) and temperature (35 °C). The adsorption equilibrium was best described by the Langmuir model, with maximum adsorption capacities (qmax) of 17.89 mg/g for MB and 16.26 mg/g for AR18, and high correlation coefficients (R2 = 0.991 and 0.924). Kinetic data fitted the pseudo-second order model (R² > 0.97), indicating chemisorption as the dominant process, while the Elovich and intra-particle diffusion models further supported multilayer adsorption and intra-pore diffusion. The thermodynamic study demonstrated that adsorption proceeded spontaneously, as shown by the negative ΔG° values (− 3.29 to − 6.75 kJ/mol for MB and − 1.27 to − 9.01 kJ/mol for AR18), and was endothermic, with respective ΔH° values of 21.37 and 54.18 kJ/mol. Among the regeneration systems tested, electro-Fenton exhibited the highest recovery efficiency (75.63% for MB and 82.36% for AR18), whereas thermal regeneration showed the lowest (34.63% and 50.36%, respectively), demonstrating the superior regeneration performance of the EF method and the potential reusability of MMT@CuFe2O4 in practical dye removal applications.