<p>Non-hydrocarbon injection gases such as carbon dioxide and flue gas offer low-cost, green substitutes for traditional hydrocarbon gases to be used in enhanced oil recovery. However, issues such as asphaltene precipitation and formation damage raise doubts about their use in tight carbonate reservoirs. While CO<sub>2</sub> injection has been extensively studied, few experimental results are available for flue gas. The present paper presents a systematic experimental comparison between synthetic flue gas and CO<sub>2</sub> in eight middle flooding experiments with recombined live oil and two low-permeability carbonate cores. The effects of gas type, pressure, volume of gas injected, and temperature on oil recovery, asphaltene deposition, and permeability damage were evaluated. CO<sub>2</sub> injection resulted in about 15% more oil recovery than was obtained with flue gas at equal pressure. Equal oil recovery was achieved by the injection of flue gas at 20 to 30% higher pressure and 10 to 15% lower volume of gas. CO<sub>2</sub> even caused up to 18.6% higher asphaltene deposition and 67% more formation damage than flue gas under identical conditions. The influence of injection pressure and temperature on the formation damage behavior has also been discussed in this study. The results confirm that flue gas injection is an applicable alternative to CO<sub>2</sub> for EOR in carbonate reservoirs.</p>

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Comprehensive experimental study to compare the effects of flue gases and CO2 injection on enhancing oil recovery and asphaltene deposition

  • Keyvan Eghtedari,
  • Parviz Darvishi,
  • Asghar Lashanizadegan,
  • Shahin Kord

摘要

Non-hydrocarbon injection gases such as carbon dioxide and flue gas offer low-cost, green substitutes for traditional hydrocarbon gases to be used in enhanced oil recovery. However, issues such as asphaltene precipitation and formation damage raise doubts about their use in tight carbonate reservoirs. While CO2 injection has been extensively studied, few experimental results are available for flue gas. The present paper presents a systematic experimental comparison between synthetic flue gas and CO2 in eight middle flooding experiments with recombined live oil and two low-permeability carbonate cores. The effects of gas type, pressure, volume of gas injected, and temperature on oil recovery, asphaltene deposition, and permeability damage were evaluated. CO2 injection resulted in about 15% more oil recovery than was obtained with flue gas at equal pressure. Equal oil recovery was achieved by the injection of flue gas at 20 to 30% higher pressure and 10 to 15% lower volume of gas. CO2 even caused up to 18.6% higher asphaltene deposition and 67% more formation damage than flue gas under identical conditions. The influence of injection pressure and temperature on the formation damage behavior has also been discussed in this study. The results confirm that flue gas injection is an applicable alternative to CO2 for EOR in carbonate reservoirs.