<p>A high-performance Ce<sup>3+</sup>-doped (Gd, Tb)<sub>3</sub>(Ga, Al)<sub>5</sub>O<sub>12</sub> (GTAGG: Ce) single crystal was engineered and characterized, demonstrating a high application potential for advanced X-ray imaging. A transparent 1-inch diameter single crystal was grown using the Czochralski method, demonstrating a significant advancement in large-scale scintillator production. Comprehensive characterization using X-ray diffraction and electron probe micro-analysis confirmed the crystal’s structural integrity. Photoluminescence and radioluminescence spectroscopy demonstrated efficient bidirectional energy transfer between Ce<sup>3+</sup> and Tb<sup>3+</sup> ions, a critical mechanism enhancing the performance of the scintillator. X-ray imaging tests were performed using crystals with a thickness of 100&#xa0;μm at the Aichi Synchrotron Radiation Center. Comparison with the industry-standard LuAG: Ce scintillator showed that the GTAGG: Ce crystal produced 2.4 times higher light output and achieved a high spatial resolution of 0.85&#xa0;μm. The results indicated that GTAGG: Ce is suitable for the next generation of high-performance X-ray imaging detectors in scientific and medical imaging applications.</p>

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Crystal growth and characterization of 1-inch GTAGG: Ce single crystal for sub-micron resolution synchrotron radiation X-ray imaging

  • Kazuya Omuro,
  • Masao Yoshino,
  • Liudmila Gushchina,
  • Seiichi Yamamoto,
  • Kohei Nakanishi,
  • Kei Kamada,
  • Karol Bartosiewicz,
  • Kyoung Jin Kim,
  • Takahiko Horiai,
  • Rikito Murakami,
  • Akihiro Yamaji,
  • Takashi Hanada,
  • Yuui Yokota,
  • Shunsuke Kurosawa,
  • Yuji Ohashi,
  • Hiroki Sato,
  • Jun Kataoka,
  • Akira Yoshikawa

摘要

A high-performance Ce3+-doped (Gd, Tb)3(Ga, Al)5O12 (GTAGG: Ce) single crystal was engineered and characterized, demonstrating a high application potential for advanced X-ray imaging. A transparent 1-inch diameter single crystal was grown using the Czochralski method, demonstrating a significant advancement in large-scale scintillator production. Comprehensive characterization using X-ray diffraction and electron probe micro-analysis confirmed the crystal’s structural integrity. Photoluminescence and radioluminescence spectroscopy demonstrated efficient bidirectional energy transfer between Ce3+ and Tb3+ ions, a critical mechanism enhancing the performance of the scintillator. X-ray imaging tests were performed using crystals with a thickness of 100 μm at the Aichi Synchrotron Radiation Center. Comparison with the industry-standard LuAG: Ce scintillator showed that the GTAGG: Ce crystal produced 2.4 times higher light output and achieved a high spatial resolution of 0.85 μm. The results indicated that GTAGG: Ce is suitable for the next generation of high-performance X-ray imaging detectors in scientific and medical imaging applications.