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<p>This study presents an appealing approach to sustainable catalysis using cellulose filter paper as a support for copper-catalyzed reactions. The paper was functionalized with thiol groups through a reaction with thioglycolic acid, which served a dual purpose: partially reducing Cu(II) to Cu(I) and stabilizing active copper species via Cu–S interactions. Spectroscopic analysis confirmed the formation of highly dispersed multi-valent Cu<sub>2</sub>O/CuO on the thiol-functionalized cellulose, resulting in a highly efficient copper catalyst. This catalyst demonstrated excellent performance in the oxidative coupling of various amines to imines, achieving yields of 39–99% within 10–30&#xa0;min. A key advantage of this system is its reusability; the catalyst maintained remarkable stability and activity over ten reaction cycles with straightforward recovery. This paper-based catalyst offers a promising strategy for eco-friendly and cost-effective synthetic processes, with significant implications for green chemistry and industrial applications.</p>

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Copper-supported thiol-functionalized cellulose as a paper-based catalyst for imine synthesis

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年3月22日

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  • Jariyaporn Sangkaworn,
  • Waranya Limprasart,
  • Mark Valentin Höfler,
  • Torsten Gutmann,
  • Soraya Pornsuwan,
  • Thanthapatra Bunchuay,
  • Jonggol Tantirungrotechai

摘要

This study presents an appealing approach to sustainable catalysis using cellulose filter paper as a support for copper-catalyzed reactions. The paper was functionalized with thiol groups through a reaction with thioglycolic acid, which served a dual purpose: partially reducing Cu(II) to Cu(I) and stabilizing active copper species via Cu–S interactions. Spectroscopic analysis confirmed the formation of highly dispersed multi-valent Cu2O/CuO on the thiol-functionalized cellulose, resulting in a highly efficient copper catalyst. This catalyst demonstrated excellent performance in the oxidative coupling of various amines to imines, achieving yields of 39–99% within 10–30 min. A key advantage of this system is its reusability; the catalyst maintained remarkable stability and activity over ten reaction cycles with straightforward recovery. This paper-based catalyst offers a promising strategy for eco-friendly and cost-effective synthetic processes, with significant implications for green chemistry and industrial applications.