<p>A practical and efficient method for synthesizing C–O cross-coupling has been established using a Pd complex anchored on mesoporous KIT-6. This design showcases exceptional efficiency, recoverability, and thermal stability. The synthesized mesostructure underwent comprehensive characterization through techniques such as FT-IR, SEM, XRD, EDX, BET, ICP, and TGA analyses. This catalyst was then successfully applied in C–O cross-coupling reactions. The approach offers several advantages, including rapid reaction times, high yields, excellent product purity, simplicity, environmental friendliness, and straightforward work-up procedures. Importantly, the durable nanohybrid catalyst exhibited no metal leaching and retained its catalytic performance across multiple cycles of use.</p>

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KIT-6 supported PhAA-Pd complex as a sustainable nanocatalyst for C–O coupling reactions

  • Abdulrahman A. Almehizia,
  • Munthar Kadhim Abosaoda,
  • Anjan Kumar,
  • Vicky Jain,
  • Suhas Ballal,
  • Abhayveer Singh,
  • Mamata Chahar,
  • Suman Saini,
  • Kamal Kant Joshi,
  • Abhinav Kumar

摘要

A practical and efficient method for synthesizing C–O cross-coupling has been established using a Pd complex anchored on mesoporous KIT-6. This design showcases exceptional efficiency, recoverability, and thermal stability. The synthesized mesostructure underwent comprehensive characterization through techniques such as FT-IR, SEM, XRD, EDX, BET, ICP, and TGA analyses. This catalyst was then successfully applied in C–O cross-coupling reactions. The approach offers several advantages, including rapid reaction times, high yields, excellent product purity, simplicity, environmental friendliness, and straightforward work-up procedures. Importantly, the durable nanohybrid catalyst exhibited no metal leaching and retained its catalytic performance across multiple cycles of use.