Scholarlink

<p>Mn-doped ZnO thin films with varying Mn concentrations were synthesized on glass substrates using the pneumatic spray technique. Energy-dispersive X-ray (EDX) analysis confirmed the substitution of Zn by Mn in the ZnO matrix. X-ray photoelectron spectroscopy (XPS) revealed characteristic spin-orbit energy states of Zn:2p and Mn:3d, indicating strong Mn-ZnO interactions. Microstructural analysis showed non-uniform extended lines and spherical grains, with decreasing grain size as Mn concentration increased. X-ray diffraction (XRD) confirmed a polycrystalline hexagonal structure, with experimentally determined lattice parameters a = 3.1453 Å, c = 5.1353 Å, in agreement with CASTEP calculations. Optical measurements indicated ~ 80% absorbance in the visible range, with a shift from blue to red as Mn content increased, suggesting bandgap modulation. These findings highlight the potential of Mn-doped ZnO films for tunable optoelectronic applications.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Experimental investigation of structural and optical properties of Mn-doped ZnO thin films deposited by pneumatic spray technique

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2025年2月27日

查看全文
  • Abdelghani Rahal,
  • Idris Bouchama,
  • M. A. Ghebouli,
  • Faisal Katib Alanazi,
  • B. Ghebouli,
  • M. Fatmi,
  • T. Chihi,
  • Talal M. Althagafi,
  • Khatir Khettab

摘要

Mn-doped ZnO thin films with varying Mn concentrations were synthesized on glass substrates using the pneumatic spray technique. Energy-dispersive X-ray (EDX) analysis confirmed the substitution of Zn by Mn in the ZnO matrix. X-ray photoelectron spectroscopy (XPS) revealed characteristic spin-orbit energy states of Zn:2p and Mn:3d, indicating strong Mn-ZnO interactions. Microstructural analysis showed non-uniform extended lines and spherical grains, with decreasing grain size as Mn concentration increased. X-ray diffraction (XRD) confirmed a polycrystalline hexagonal structure, with experimentally determined lattice parameters a = 3.1453 Å, c = 5.1353 Å, in agreement with CASTEP calculations. Optical measurements indicated ~ 80% absorbance in the visible range, with a shift from blue to red as Mn content increased, suggesting bandgap modulation. These findings highlight the potential of Mn-doped ZnO films for tunable optoelectronic applications.