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<p>Efficient catalysts for soot oxidation are critical for mitigating environmental pollution. In this study, CoMn<sub>2</sub>O<sub>4</sub> spinel catalysts were synthesised using reverse co-precipitation and co-precipitation methods to evaluate their performance in soot oxidation and kinetic behaviour. All samples exhibited a tetragonal phase (XRD) and spherical morphology with rough surfaces (SEM). Raman spectroscopy confirmed structural disorder and oxygen vacancies, while XPS analysis revealed the presence of low-valence Mn ions, facilitating oxygen vacancy formation critical for soot oxidation. Additionally, the co-existence of Co and Mn ions contributed to a synergistic effect, enhancing the catalytic properties of the spinel structure. The reverse co-precipitation method produced a catalyst with a higher concentration of oxygen vacancies and active oxygen species among the samples. This sample demonstrated superior catalytic performance, achieving a T<sub>50%</sub> of 424&#xa0;°C, low activation energy (153&#xa0;kJ/mol) and pre-exponential factor (25&#xa0;min<sup>− 1</sup>). Soot TPR analysis highlighted the role of catalyst reducibility, while thermogravimetric analysis revealed that activation energy and pre-exponential factors were influenced by surface composition. These findings provide valuable insights into the design of efficient catalysts for soot oxidation, emphasising the importance of synthesis methods and surface characteristics.</p>

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Potential of CoMn2O4 spinel as soot oxidation catalyst and its kinetics thereof

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年1月7日

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  • R. Nithya,
  • Sunaina S. Patil,
  • Hari Prasad Dasari,
  • Harshini Dasari,
  • S. Nethaji

摘要

Efficient catalysts for soot oxidation are critical for mitigating environmental pollution. In this study, CoMn2O4 spinel catalysts were synthesised using reverse co-precipitation and co-precipitation methods to evaluate their performance in soot oxidation and kinetic behaviour. All samples exhibited a tetragonal phase (XRD) and spherical morphology with rough surfaces (SEM). Raman spectroscopy confirmed structural disorder and oxygen vacancies, while XPS analysis revealed the presence of low-valence Mn ions, facilitating oxygen vacancy formation critical for soot oxidation. Additionally, the co-existence of Co and Mn ions contributed to a synergistic effect, enhancing the catalytic properties of the spinel structure. The reverse co-precipitation method produced a catalyst with a higher concentration of oxygen vacancies and active oxygen species among the samples. This sample demonstrated superior catalytic performance, achieving a T50% of 424 °C, low activation energy (153 kJ/mol) and pre-exponential factor (25 min− 1). Soot TPR analysis highlighted the role of catalyst reducibility, while thermogravimetric analysis revealed that activation energy and pre-exponential factors were influenced by surface composition. These findings provide valuable insights into the design of efficient catalysts for soot oxidation, emphasising the importance of synthesis methods and surface characteristics.