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<p>A series of glass samples with the nominal composition 65SiO<sub>2</sub> - (22.5-x) Li<sub>2</sub>O − 12.5Al<sub>2</sub>O<sub>3</sub> - xTiO<sub>2</sub>, where x varies as 2.5, 5, 7.5, and 10&#xa0;mol%, were synthesized using the conventional melt-quenching technique. Differential scanning calorimetry (DSC) was utilized to identify crucial thermal transitions, which informed the process of fabricating corresponding glass-ceramic derivatives. X-ray diffraction (XRD) analysis confirmed the formation of three primary crystalline phases in the glass-ceramics: lithium disilicate (Li₂Si<sub>2</sub>O<sub>5</sub>), lithium aluminosilicate (LiAlSiO<sub>4</sub>), and brookite (TiO<sub>2</sub>). Scanning electron microscopy (SEM) combined with energy-dispersive X-ray spectroscopy (EDAX) demonstrated that crystal growth increased in size and developed well-defined morphologies. Vickers microhardness testing indicated that TiO<sub>2</sub>-doped lithium silicate glasses and their glass-ceramic counterparts exhibit mechanical properties compatible with dental application requirements. Differential scanning calorimetry (DSC) analysis revealed that increasing TiO<sub>2</sub> content (2.5–10&#xa0;mol%) shifted thermal transitions to higher temperatures, indicating improved thermal stability and a stronger glass network. Higher TiO<sub>2</sub> also enhanced microhardness (5.02–5.93 GPa) and compressive strength (440–542&#xa0;MPa), with further gains after heat treatment due to TiO<sub>2</sub>-induced crystallization of hard phases. Corresponding glass-ceramics showed increased hardness (5.51–7.27 GPa), compressive strength (492–583&#xa0;MPa), and density (2.478–3.441&#xa0;g/cm³), confirming the reinforcing and densifying effects of TiO<sub>2</sub>. Fourier transform infrared spectroscopy (FTIR) results suggested that modifiers such as Li<sub>2</sub>O and TiO<sub>2</sub> disrupt the SiO<sub>4</sub> tetrahedral network by introducing non-bridging oxygens (NBOs) and weakening some bonds, thereby affecting network polymerization and structural rigidity. TiO₂ incorporation enhanced thermal stability, hardness, and compressive strength, with further gains after heat treatment due to TiO<sub>2</sub>-induced crystallization. FTIR analysis confirmed structural modifications promoting a stronger glass network. These improvements yield glass-ceramics with mechanical and thermal properties comparable to dental enamel, enhancing their suitability for restorative applications.</p>

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Effect of TiO2 doping on the structure and properties of lithium silicate-based glass-ceramics for potential dental applications

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2026年1月26日

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  • M. A. Marzouk,
  • R. L. Elwan,
  • A. M. Fayad,
  • F. H. Elbatal,
  • M. A. Azooz,
  • M. A. Ouis,
  • A. Kh. Helmy,
  • Y. M. Hamdy

摘要

A series of glass samples with the nominal composition 65SiO2 - (22.5-x) Li2O − 12.5Al2O3 - xTiO2, where x varies as 2.5, 5, 7.5, and 10 mol%, were synthesized using the conventional melt-quenching technique. Differential scanning calorimetry (DSC) was utilized to identify crucial thermal transitions, which informed the process of fabricating corresponding glass-ceramic derivatives. X-ray diffraction (XRD) analysis confirmed the formation of three primary crystalline phases in the glass-ceramics: lithium disilicate (Li₂Si2O5), lithium aluminosilicate (LiAlSiO4), and brookite (TiO2). Scanning electron microscopy (SEM) combined with energy-dispersive X-ray spectroscopy (EDAX) demonstrated that crystal growth increased in size and developed well-defined morphologies. Vickers microhardness testing indicated that TiO2-doped lithium silicate glasses and their glass-ceramic counterparts exhibit mechanical properties compatible with dental application requirements. Differential scanning calorimetry (DSC) analysis revealed that increasing TiO2 content (2.5–10 mol%) shifted thermal transitions to higher temperatures, indicating improved thermal stability and a stronger glass network. Higher TiO2 also enhanced microhardness (5.02–5.93 GPa) and compressive strength (440–542 MPa), with further gains after heat treatment due to TiO2-induced crystallization of hard phases. Corresponding glass-ceramics showed increased hardness (5.51–7.27 GPa), compressive strength (492–583 MPa), and density (2.478–3.441 g/cm³), confirming the reinforcing and densifying effects of TiO2. Fourier transform infrared spectroscopy (FTIR) results suggested that modifiers such as Li2O and TiO2 disrupt the SiO4 tetrahedral network by introducing non-bridging oxygens (NBOs) and weakening some bonds, thereby affecting network polymerization and structural rigidity. TiO₂ incorporation enhanced thermal stability, hardness, and compressive strength, with further gains after heat treatment due to TiO2-induced crystallization. FTIR analysis confirmed structural modifications promoting a stronger glass network. These improvements yield glass-ceramics with mechanical and thermal properties comparable to dental enamel, enhancing their suitability for restorative applications.