Scholarlink

<p>The growing need for efficient energy storage has revealed key limitations in conventional battery-type electrodes, particularly their low electrical conductivity and limited cycling stability. To address this issue, a Bi-1,4-benzenedicarboxylate (Bi-OF) metal organic framework was synthesized in the form of nanosheets using a simple solvothermal method. The structure of Bi-OF was examined using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy&#xa0;(TEM). The Bi-OF material was used to modify the glassy carbon electrode (GCE), and its electrochemical performance was systematically evaluated. Its electrochemical behavior was evaluated through cyclic voltammetry (CV), charge-discharge (CD) testing, and electrochemical impedance spectroscopy (EIS). The Bi-OF electrode achieved a high specific capacitance of 1797.88&#xa0;C·g⁻¹ (1284.2&#xa0;F·g⁻¹) at 2.0&#xa0;A·g<sup>−1</sup>. It also showed low internal resistance (110 Ω) and maintained 84.7% of its initial capacitance after 3000 cycles. These results suggest that Bi-OF is a promising candidate for high-performance and environmentally friendly supercapacitor applications.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Structural and electrochemical insights into bismuth-based metal organic framework for capacitive applications

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2025年12月11日

查看全文
  • Mona Elfiky,
  • Aya Elleboudy,
  • Nehal Salahuddin

摘要

The growing need for efficient energy storage has revealed key limitations in conventional battery-type electrodes, particularly their low electrical conductivity and limited cycling stability. To address this issue, a Bi-1,4-benzenedicarboxylate (Bi-OF) metal organic framework was synthesized in the form of nanosheets using a simple solvothermal method. The structure of Bi-OF was examined using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The Bi-OF material was used to modify the glassy carbon electrode (GCE), and its electrochemical performance was systematically evaluated. Its electrochemical behavior was evaluated through cyclic voltammetry (CV), charge-discharge (CD) testing, and electrochemical impedance spectroscopy (EIS). The Bi-OF electrode achieved a high specific capacitance of 1797.88 C·g⁻¹ (1284.2 F·g⁻¹) at 2.0 A·g−1. It also showed low internal resistance (110 Ω) and maintained 84.7% of its initial capacitance after 3000 cycles. These results suggest that Bi-OF is a promising candidate for high-performance and environmentally friendly supercapacitor applications.