<p>We investigated the relative contributions of various factors that influence seasonal changes in sea surface partial pressure of <InlineEquation ID="IEq3"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_12720_Article_IEq3.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="32" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {CO}_{2}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>CO</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation> (<InlineEquation ID="IEq4"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_12720_Article_IEq1.gif" Format="GIF" Height="18" Rendition="HTML" Resolution="72" Type="Linedraw" Width="41" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {pCO}_{2}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>pCO</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation>, calculated from the measured pH and total alkalinity) in four regions of northwestern Greenland: Nares Strait, Lincoln Sea, Sherard Osborn and Petermann fjords. Using the temperature minimum layer as a proxy for winter conditions, we examined <InlineEquation ID="IEq5"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_12720_Article_IEq1.gif" Format="GIF" Height="18" Rendition="HTML" Resolution="72" Type="Linedraw" Width="41" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {pCO}_{2}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>pCO</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation> dynamics from the onset of sea-ice melt to summer. Our findings revealed significant spatial variability in <InlineEquation ID="IEq6"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_12720_Article_IEq1.gif" Format="GIF" Height="18" Rendition="HTML" Resolution="72" Type="Linedraw" Width="41" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {pCO}_{2}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>pCO</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation>, driven by differences in temperature, freshwater inputs, and biological activity. In particular, in Sherard Osborn Fjord substantial freshwater inputs and strong stratification were found to enhance <InlineEquation ID="IEq7"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_12720_Article_IEq1.gif" Format="GIF" Height="18" Rendition="HTML" Resolution="72" Type="Linedraw" Width="41" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {pCO}_{2}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>pCO</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation> accumulation, while in Petermann Fjord biological <InlineEquation ID="IEq8"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_12720_Article_IEq3.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="32" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {CO}_{2}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>CO</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation> uptake was the main driver. This study, conducted in summer 2019, underscores the critical role of northwest Greenland’s coastal waters as a summer <InlineEquation ID="IEq9"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_12720_Article_IEq3.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="32" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {CO}_{2}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>CO</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation> sink. It highlights the complex interplay of physical and biogeochemical processes in modulating <InlineEquation ID="IEq10"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_12720_Article_IEq1.gif" Format="GIF" Height="18" Rendition="HTML" Resolution="72" Type="Linedraw" Width="41" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {pCO}_{2}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>pCO</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation>, suggesting significant regional differences in <InlineEquation ID="IEq11"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_12720_Article_IEq3.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="32" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {CO}_{2}\)</EquationSource> <EquationSource Format="MATHML"><math> <msub> <mtext>CO</mtext> <mn>2</mn> </msub> </math></EquationSource> </InlineEquation> dynamics between two neighboring fjords.</p>

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Unraveling ocean \(\hbox {pCO}_{2}\) dynamics in Northwest Greenland Fjords

  • Camille Hayatte Akhoudas,
  • Adam Ulfsbo,
  • Brett F. Thornton,
  • John W. Pohlman,
  • Lee-Gray Boze,
  • Martin Jakobsson,
  • Christian Stranne

摘要

We investigated the relative contributions of various factors that influence seasonal changes in sea surface partial pressure of \(\hbox {CO}_{2}\) CO 2 ( \(\hbox {pCO}_{2}\) pCO 2 , calculated from the measured pH and total alkalinity) in four regions of northwestern Greenland: Nares Strait, Lincoln Sea, Sherard Osborn and Petermann fjords. Using the temperature minimum layer as a proxy for winter conditions, we examined \(\hbox {pCO}_{2}\) pCO 2 dynamics from the onset of sea-ice melt to summer. Our findings revealed significant spatial variability in \(\hbox {pCO}_{2}\) pCO 2 , driven by differences in temperature, freshwater inputs, and biological activity. In particular, in Sherard Osborn Fjord substantial freshwater inputs and strong stratification were found to enhance \(\hbox {pCO}_{2}\) pCO 2 accumulation, while in Petermann Fjord biological \(\hbox {CO}_{2}\) CO 2 uptake was the main driver. This study, conducted in summer 2019, underscores the critical role of northwest Greenland’s coastal waters as a summer \(\hbox {CO}_{2}\) CO 2 sink. It highlights the complex interplay of physical and biogeochemical processes in modulating \(\hbox {pCO}_{2}\) pCO 2 , suggesting significant regional differences in \(\hbox {CO}_{2}\) CO 2 dynamics between two neighboring fjords.