<p>The world needs clean energy. One of the most promising ways of producing it in large amounts is the helium3-deuterium (<sup>3</sup><InlineEquation ID="IEq1"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_5542_Article_IEq1.gif" Format="GIF" Height="14" Rendition="HTML" Resolution="72" Type="Linedraw" Width="39" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {He-D}\)</EquationSource> <EquationSource Format="MATHML"><math> <mtext>He-D</mtext> </math></EquationSource> </InlineEquation>) fusion reaction. Although there are numerous sources of <sup>3</sup><InlineEquation ID="IEq2"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_5542_Article_IEq2.gif" Format="GIF" Height="14" Rendition="HTML" Resolution="72" Type="Linedraw" Width="21" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {He}\)</EquationSource> <EquationSource Format="MATHML"><math> <mtext>He</mtext> </math></EquationSource> </InlineEquation> on Earth, most of them are either difficult to access or unprofitable to operate. The main problem underlying the shortage of <sup>3</sup><InlineEquation ID="IEq3"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_5542_Article_IEq2.gif" Format="GIF" Height="14" Rendition="HTML" Resolution="72" Type="Linedraw" Width="21" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {He}\)</EquationSource> <EquationSource Format="MATHML"><math> <mtext>He</mtext> </math></EquationSource> </InlineEquation> is the lack of an effective method of obtaining this isotope. Here we report the results of quantum filtration of <sup>3</sup><InlineEquation ID="IEq4"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_5542_Article_IEq2.gif" Format="GIF" Height="14" Rendition="HTML" Resolution="72" Type="Linedraw" Width="21" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {He}\)</EquationSource> <EquationSource Format="MATHML"><math> <mtext>He</mtext> </math></EquationSource> </InlineEquation> from liquid helium in a superfluid state (below the <InlineEquation ID="IEq5"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_5542_Article_IEq5.gif" Format="GIF" Height="14" Rendition="HTML" Resolution="72" Type="Linedraw" Width="15" /> </InlineMediaObject> <EquationSource Format="TEX">\(\lambda\)</EquationSource> <EquationSource Format="MATHML"><math> <mi>λ</mi> </math></EquationSource> </InlineEquation>-transition), with the use of an entropy filter made of a high-temperature superconductor YBCO-123. During the operation of so-called <i>fountain effect</i> generated with this filter, unlike the other filters, we observed a strong increase of <sup>3</sup><InlineEquation ID="IEq6"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_5542_Article_IEq2.gif" Format="GIF" Height="14" Rendition="HTML" Resolution="72" Type="Linedraw" Width="21" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {He}\)</EquationSource> <EquationSource Format="MATHML"><math> <mtext>He</mtext> </math></EquationSource> </InlineEquation> concentration downstream, where only pure <InlineEquation ID="IEq7"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_5542_Article_IEq7.gif" Format="GIF" Height="16" Rendition="HTML" Resolution="72" Type="Linedraw" Width="27" /> </InlineMediaObject> <EquationSource Format="TEX">\(^{4}\hbox {He}\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mmultiscripts> <mrow /> <mrow /> <mn>4</mn> </mmultiscripts> <mtext>He</mtext> </mrow> </math></EquationSource> </InlineEquation> was expected. This effect occurred due to the unique combination of two quantum phenomena—superfluidity and superconductivity, leading to the observation of a low-temperature rectification-like process. Rectification of helium isotopes does not require lowering the temperature below the <InlineEquation ID="IEq8"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_5542_Article_IEq5.gif" Format="GIF" Height="14" Rendition="HTML" Resolution="72" Type="Linedraw" Width="15" /> </InlineMediaObject> <EquationSource Format="TEX">\(\lambda\)</EquationSource> <EquationSource Format="MATHML"><math> <mi>λ</mi> </math></EquationSource> </InlineEquation>-transition, so the process can be more economical than filtration. Moreover, micro-superconductors could be applied also to the extraction of deuterium, thus allowing the same method to be used for both crucial components of the <sup>3</sup><InlineEquation ID="IEq9"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_5542_Article_IEq1.gif" Format="GIF" Height="14" Rendition="HTML" Resolution="72" Type="Linedraw" Width="39" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {He-D}\)</EquationSource> <EquationSource Format="MATHML"><math> <mtext>He-D</mtext> </math></EquationSource> </InlineEquation> fusion. This method should be easy to upscale and could be used in space (with less energy input) as <sup>3</sup><InlineEquation ID="IEq10"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41598_2025_5542_Article_IEq2.gif" Format="GIF" Height="14" Rendition="HTML" Resolution="72" Type="Linedraw" Width="21" /> </InlineMediaObject> <EquationSource Format="TEX">\(\hbox {He}\)</EquationSource> <EquationSource Format="MATHML"><math> <mtext>He</mtext> </math></EquationSource> </InlineEquation>, the crucial isotope for future energy, is also sought beyond the Earth.</p>

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When superfluidity meets superconductivity in the extraction of 3He isotope from liquid helium

  • Wojciech Kempiński,
  • Piotr Banat,
  • Mateusz Kempiński,
  • Zbigniew Trybuła,
  • Jakub Niechciał,
  • Maciej Chorowski,
  • Jarosław Poliński,
  • Katarzyna Chołast

摘要

The world needs clean energy. One of the most promising ways of producing it in large amounts is the helium3-deuterium (3 \(\hbox {He-D}\) He-D ) fusion reaction. Although there are numerous sources of 3 \(\hbox {He}\) He on Earth, most of them are either difficult to access or unprofitable to operate. The main problem underlying the shortage of 3 \(\hbox {He}\) He is the lack of an effective method of obtaining this isotope. Here we report the results of quantum filtration of 3 \(\hbox {He}\) He from liquid helium in a superfluid state (below the \(\lambda\) λ -transition), with the use of an entropy filter made of a high-temperature superconductor YBCO-123. During the operation of so-called fountain effect generated with this filter, unlike the other filters, we observed a strong increase of 3 \(\hbox {He}\) He concentration downstream, where only pure \(^{4}\hbox {He}\) 4 He was expected. This effect occurred due to the unique combination of two quantum phenomena—superfluidity and superconductivity, leading to the observation of a low-temperature rectification-like process. Rectification of helium isotopes does not require lowering the temperature below the \(\lambda\) λ -transition, so the process can be more economical than filtration. Moreover, micro-superconductors could be applied also to the extraction of deuterium, thus allowing the same method to be used for both crucial components of the 3 \(\hbox {He-D}\) He-D fusion. This method should be easy to upscale and could be used in space (with less energy input) as 3 \(\hbox {He}\) He , the crucial isotope for future energy, is also sought beyond the Earth.