<p>Quantum dot (QD) superlattices offer collective optoelectronic properties distinct from disordered solids<sup><CitationRef AdditionalCitationIDS="CR2 CR3" CitationID="CR1">1</CitationRef>–<CitationRef CitationID="CR4">4</CitationRef></sup>, but their integration into high-resolution display devices remains elusive because of difficulties in achieving spatially defined, structurally coherent thin films. Here we report a scalable strategy for fabricating pixelated perovskite QD (PeQD) superlattice thin-film arrays that feature in-plane long-range order, vertical confinement and precise spatial patterning. By engineering rhombic dodecahedral CsPbBr<sub>3</sub> nanocrystals with robust surface termination by a ligand-fluoride co-stabilization approach, we direct the formation of hexagonally close-packed superlattice films using capillary liquid-bridge confined assembly. These superlattice films exhibit reduced energetic disorder and enhanced electronic coupling. When integrated into light-emitting diodes (LEDs), the electrically driven PeQD superlattices yield an external quantum efficiency of 30.9%, high luminance of&#xa0;117,144 cd m<sup>−2</sup> and pixel densities of up to 5,080 pixels per inch. The devices show an extrapolated operational half-lifetime (<i>T</i><sub>50</sub>) of 12,411 h at 100 cd m<sup>−2</sup>—more than 1,000-fold longer than previously reported pixelated PeQD LEDs. Moreover, we demonstrate the direct integration of patterned superlattices onto a commercial thin-film transistor backplane to construct a 1.85-inch active-matrix display with full greyscale control and video playback ability. These results establish colloidal QD superlattices as a viable material platform for next-generation high-resolution, stable and efficient perovskite displays.</p>

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Pixelated quantum-dot superlattice LEDs

  • Chengxi Zhang,
  • Qingsen Zeng,
  • Hui Li,
  • Renjun Guo,
  • Yue Yu,
  • Linjie Dai,
  • Lyudmila Turyanska,
  • Zirui Liu,
  • Jun Dai,
  • Yingguo Yang,
  • Yue Zhao,
  • Jun Lu,
  • Lin Wang,
  • Lingmei Kong,
  • Tze Chien Sum,
  • Yuchen Wu,
  • Tae-Woo Lee,
  • Xuyong Yang

摘要

Quantum dot (QD) superlattices offer collective optoelectronic properties distinct from disordered solids14, but their integration into high-resolution display devices remains elusive because of difficulties in achieving spatially defined, structurally coherent thin films. Here we report a scalable strategy for fabricating pixelated perovskite QD (PeQD) superlattice thin-film arrays that feature in-plane long-range order, vertical confinement and precise spatial patterning. By engineering rhombic dodecahedral CsPbBr3 nanocrystals with robust surface termination by a ligand-fluoride co-stabilization approach, we direct the formation of hexagonally close-packed superlattice films using capillary liquid-bridge confined assembly. These superlattice films exhibit reduced energetic disorder and enhanced electronic coupling. When integrated into light-emitting diodes (LEDs), the electrically driven PeQD superlattices yield an external quantum efficiency of 30.9%, high luminance of 117,144 cd m−2 and pixel densities of up to 5,080 pixels per inch. The devices show an extrapolated operational half-lifetime (T50) of 12,411 h at 100 cd m−2—more than 1,000-fold longer than previously reported pixelated PeQD LEDs. Moreover, we demonstrate the direct integration of patterned superlattices onto a commercial thin-film transistor backplane to construct a 1.85-inch active-matrix display with full greyscale control and video playback ability. These results establish colloidal QD superlattices as a viable material platform for next-generation high-resolution, stable and efficient perovskite displays.