<p>Elastocaloric cooling using shape-memory alloys (SMAs) is a promising greenhouse gas (GHG)-free alternative to conventional vapour-compression refrigeration that relies on high global warming potential (GWP) gas refrigerants<sup><CitationRef AdditionalCitationIDS="CR2 CR3" CitationID="CR1">1</CitationRef>–<CitationRef CitationID="CR4">4</CitationRef></sup>. However, existing elastocaloric systems have not yet reached sub-zero Celsius temperatures, which restricts their application in various freezing scenarios<sup><CitationRef CitationID="CR5">5</CitationRef>,<CitationRef CitationID="CR6">6</CitationRef></sup>. Here we constructed a compression-based, regenerative elastocaloric cooling device using low-transition-temperature tubular NiTi units in a cascaded configuration. The selected NiTi alloy exhibited superelasticity and substantial entropy changes down to −20 °C. Moreover, low-freezing-point aqueous calcium chloride solution was used as the heat-transfer fluid, ensuring effective flow at low operational temperatures. Our desktop device achieved a heat-source temperature of −12 °C from a room-temperature heat sink, paving the way for next-generation green elastocaloric freezing technologies.</p>

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Sub-zero Celsius elastocaloric cooling via low-transition-temperature alloys

  • Guoan Zhou,
  • Zexi Li,
  • Zhongzheng Deng,
  • Shuhuai Yao,
  • Ali Safari,
  • Lingyun Zhang,
  • Peng Hua,
  • Qingping Sun

摘要

Elastocaloric cooling using shape-memory alloys (SMAs) is a promising greenhouse gas (GHG)-free alternative to conventional vapour-compression refrigeration that relies on high global warming potential (GWP) gas refrigerants14. However, existing elastocaloric systems have not yet reached sub-zero Celsius temperatures, which restricts their application in various freezing scenarios5,6. Here we constructed a compression-based, regenerative elastocaloric cooling device using low-transition-temperature tubular NiTi units in a cascaded configuration. The selected NiTi alloy exhibited superelasticity and substantial entropy changes down to −20 °C. Moreover, low-freezing-point aqueous calcium chloride solution was used as the heat-transfer fluid, ensuring effective flow at low operational temperatures. Our desktop device achieved a heat-source temperature of −12 °C from a room-temperature heat sink, paving the way for next-generation green elastocaloric freezing technologies.