<p>Even with the rapid development of renewable energy sources, improving the efficiency of energy conversion from fossil or synthetic fuels remains a challenge because, for example, combustion engines in long-range aircraft will still be needed in the upcoming decades<sup><CitationRef CitationID="CR1">1</CitationRef></sup>. Increasing their operating temperatures (1,050–1,150 °C (refs. <sup><CitationRef AdditionalCitationIDS="CR3" CitationID="CR2">2</CitationRef>–<CitationRef CitationID="CR4">4</CitationRef></sup>)) is one option. This requires replacing single-crystalline Ni-based superalloys in the hottest sections of turbines by refractory-element-based materials, which exhibit much higher solidus temperatures beyond 2,000 °C (refs. <sup><CitationRef AdditionalCitationIDS="CR6" CitationID="CR5">5</CitationRef>–<CitationRef CitationID="CR7">7</CitationRef></sup>). Here we introduce a single-phase Cr-36.1Mo-3Si (at.%) alloy that meets, for the first time, to our knowledge, the most important critical requirements for refractory-element-based materials: (1) relevant resistance against pesting, nitridation and scale spallation at elevated temperatures, minimum up to 1,100 °C, and (2) sufficient compression ductility at room temperature. Although strength and creep resistance in such alloys were already superior to Ni-based superalloys in several cases, oxidation/corrosion resistance, mandatory to withstand the combustion atmosphere, and ductility/toughness, needed for damage tolerance and device setting, still pose barriers for the development or application of refractory-element-based candidate materials. Any previous successful attempts to address the otherwise catastrophic oxidation of Mo and nitridation of Cr during oxidation suffered from a loss in ductility at ambient temperatures.</p>

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A ductile chromium–molybdenum alloy resistant to high-temperature oxidation

  • Frauke Hinrichs,
  • Georg Winkens,
  • Lena Katharina Kramer,
  • Gabriely Falcão,
  • Ewa M. Hahn,
  • Daniel Schliephake,
  • Michael Konrad Eusterholz,
  • Sandipan Sen,
  • Mathias Christian Galetz,
  • Haruyuki Inui,
  • Alexander Kauffmann,
  • Martin Heilmaier

摘要

Even with the rapid development of renewable energy sources, improving the efficiency of energy conversion from fossil or synthetic fuels remains a challenge because, for example, combustion engines in long-range aircraft will still be needed in the upcoming decades1. Increasing their operating temperatures (1,050–1,150 °C (refs. 24)) is one option. This requires replacing single-crystalline Ni-based superalloys in the hottest sections of turbines by refractory-element-based materials, which exhibit much higher solidus temperatures beyond 2,000 °C (refs. 57). Here we introduce a single-phase Cr-36.1Mo-3Si (at.%) alloy that meets, for the first time, to our knowledge, the most important critical requirements for refractory-element-based materials: (1) relevant resistance against pesting, nitridation and scale spallation at elevated temperatures, minimum up to 1,100 °C, and (2) sufficient compression ductility at room temperature. Although strength and creep resistance in such alloys were already superior to Ni-based superalloys in several cases, oxidation/corrosion resistance, mandatory to withstand the combustion atmosphere, and ductility/toughness, needed for damage tolerance and device setting, still pose barriers for the development or application of refractory-element-based candidate materials. Any previous successful attempts to address the otherwise catastrophic oxidation of Mo and nitridation of Cr during oxidation suffered from a loss in ductility at ambient temperatures.