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<p>With their atomic precision and synthetically tailorable properties, molecules offer new possibilities for emerging computing, sensing, optical and quantum technologies. However, the scalable, damage-free integration of molecules into active devices with atomic-scale control remains a critical challenge due to incompatibility with existing top-down fabrication processes. Here we introduce self-assembled contacts, a strategy in which device structures are first fabricated using standard semiconductor manufacturing processes and subsequently transformed through engineered surface interactions to form self-aligned, pristine interfaces with molecules. We validate this approach by fabricating over 1,000 electrically active metal–molecule–metal devices with yields of up to 99% and stable operation over 10<sup>5</sup> measurement cycles, even for molecular layers thinner than 1 nm. In situ Raman measurements verified the preservation of molecular integrity. Beyond individual devices, the platform supports system-level integration, which we demonstrate through vector-matrix multiplication, a fundamental operation in neuromorphic computing, implemented in a crossbar array of self-rectified molecular memory devices. Our results establish self-assembled contacts as a scalable platform for integrating molecular functionalities into devices, bridging self-assembly and top-down manufacturing.</p>

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Self-assembled contacts for high-yield molecular devices

  • 期刊论文

  • 发表日期：

    2026年8月3日

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  • Sarah O. Spector,
  • Peter F. Satterthwaite,
  • Maxwell Conte,
  • Teddy Hsieh,
  • Eduard O. Bobylev,
  • Kieran Dunn,
  • Weikun Zhu,
  • Jinwoo Sim,
  • Jeremiah A. Johnson,
  • Farnaz Niroui

摘要

With their atomic precision and synthetically tailorable properties, molecules offer new possibilities for emerging computing, sensing, optical and quantum technologies. However, the scalable, damage-free integration of molecules into active devices with atomic-scale control remains a critical challenge due to incompatibility with existing top-down fabrication processes. Here we introduce self-assembled contacts, a strategy in which device structures are first fabricated using standard semiconductor manufacturing processes and subsequently transformed through engineered surface interactions to form self-aligned, pristine interfaces with molecules. We validate this approach by fabricating over 1,000 electrically active metal–molecule–metal devices with yields of up to 99% and stable operation over 105 measurement cycles, even for molecular layers thinner than 1 nm. In situ Raman measurements verified the preservation of molecular integrity. Beyond individual devices, the platform supports system-level integration, which we demonstrate through vector-matrix multiplication, a fundamental operation in neuromorphic computing, implemented in a crossbar array of self-rectified molecular memory devices. Our results establish self-assembled contacts as a scalable platform for integrating molecular functionalities into devices, bridging self-assembly and top-down manufacturing.