<p>Efficient wide-bandgap perovskite solar cells have pushed tandem efficiencies to 34.9%, reinforcing their promise for next-generation photovoltaics. However, their commercial adoption is hindered by stability issues of wide-bandgap perovskites, especially under high-temperature maximum power point tracking conditions. Here we report the stabilization of ~1.7-eV wide-bandgap perovskites via intermediate phase evolution, enabling a self-guided crystal-growth mode. A CsI<sub>2</sub>Br intermediate phase forms during early stage deposition, directing the oriented growth of polycrystalline films with unique texturing. Atomic-scale scanning transmission electron microscopy reveals that the CsI<sub>2</sub>Br <InlineEquation ID="IEq1"> <EquationSource Format="TEX">\((1\bar{2}3)\)</EquationSource> <EquationSource Format="MATHML"><math> <mrow> <mo>(</mo> <mrow> <mn>1</mn> <mover accent="true"> <mrow> <mn>2</mn> </mrow> <mo>¯</mo> </mover> <mn>3</mn> </mrow> <mo>)</mo> </mrow> </math></EquationSource> </InlineEquation> facet, with a 2.9-Å interplanar spacing, matches the perovskite (200) facet, guiding coherent {100} growth. This results in enhanced crystallinity, with a 2-order-magnitude increase in the (100) diffraction intensity and a reduced full-width at half-maximum from 0.249° to 0.148°, compared with solution-processed films. The resulting solar cells exhibit outstanding thermal and operational stability, maintaining performance under maximum power point tracking for over 3,000 h at room temperature and over 500 h at 110 °C, with a projected lifetime of ~70,000 h. With 21.37% power conversion efficiency and &gt;84% fill factor, this work presents a compelling route towards stable, high-efficiency tandem photovoltaics.</p>

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Intermediate phase evolution for stable and oriented evaporated wide-bandgap perovskite solar cells

  • Zijing Dong,
  • Jingcong Hu,
  • Xiao Guo,
  • Zhuojie Shi,
  • Haijie Chen,
  • Yunluo Wang,
  • Ran Luo,
  • Julian A. Steele,
  • Zachary Degnan,
  • Eduardo Solano,
  • Qilin Zhou,
  • Nikhil Kalasariya,
  • Nengxu Li,
  • Tao Wang,
  • Jinxi Chen,
  • Ling Kai Lee,
  • Yuduan Wang,
  • Jia Li,
  • Martin Stolterfoht,
  • Manling Sui,
  • Yue Lu,
  • Yi Hou

摘要

Efficient wide-bandgap perovskite solar cells have pushed tandem efficiencies to 34.9%, reinforcing their promise for next-generation photovoltaics. However, their commercial adoption is hindered by stability issues of wide-bandgap perovskites, especially under high-temperature maximum power point tracking conditions. Here we report the stabilization of ~1.7-eV wide-bandgap perovskites via intermediate phase evolution, enabling a self-guided crystal-growth mode. A CsI2Br intermediate phase forms during early stage deposition, directing the oriented growth of polycrystalline films with unique texturing. Atomic-scale scanning transmission electron microscopy reveals that the CsI2Br \((1\bar{2}3)\) ( 1 2 ¯ 3 ) facet, with a 2.9-Å interplanar spacing, matches the perovskite (200) facet, guiding coherent {100} growth. This results in enhanced crystallinity, with a 2-order-magnitude increase in the (100) diffraction intensity and a reduced full-width at half-maximum from 0.249° to 0.148°, compared with solution-processed films. The resulting solar cells exhibit outstanding thermal and operational stability, maintaining performance under maximum power point tracking for over 3,000 h at room temperature and over 500 h at 110 °C, with a projected lifetime of ~70,000 h. With 21.37% power conversion efficiency and >84% fill factor, this work presents a compelling route towards stable, high-efficiency tandem photovoltaics.