<p>Ferroelectric materials are characterized by a parallel arrangement of electric dipoles, but at the nanoscale they can present vortices and other non-trivial topological structures<sup><CitationRef AdditionalCitationIDS="CR2 CR3 CR4 CR5 CR6 CR7 CR8" CitationID="CR1">1</CitationRef>–<CitationRef CitationID="CR9">9</CitationRef></sup> that combine small size and topological protection, rendering them functionally attractive<sup><CitationRef AdditionalCitationIDS="CR11 CR12" CitationID="CR10">10</CitationRef>–<CitationRef CitationID="CR13">13</CitationRef></sup>. The driving force for the appearance of vortices in ferroelectrics is the need to minimize the depolarizing fields at interfaces<sup><CitationRef AdditionalCitationIDS="CR4" CitationID="CR3">3</CitationRef>–<CitationRef CitationID="CR5">5</CitationRef>,<CitationRef CitationID="CR14">14</CitationRef></sup>; by making the polarization rotate, depolarization fields vanish<sup><CitationRef CitationID="CR4">4</CitationRef>,<CitationRef CitationID="CR5">5</CitationRef>,<CitationRef CitationID="CR8">8</CitationRef>,<CitationRef CitationID="CR9">9</CitationRef></sup>. Antiferroelectrics, by contrast, are defined by an antiparallel arrangement of electric dipoles<sup><CitationRef CitationID="CR15">15</CitationRef></sup>. A priori, therefore, they lack the depolarization fields that drive the appearance of non-trivial topologies in ferroelectrics. At the atomic scale of the dipoles, however, we find that polar discontinuities can still happen, driving the appearance of topological singularities at ferroelastic domain walls.</p>

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Vortices and antivortices in antiferroelectric PbZrO3

  • Ying Liu,
  • Huazhang Zhang,
  • Konstantin Shapovalov,
  • Ranming Niu,
  • Julie M. Cairney,
  • Xiaozhou Liao,
  • Krystian Roleder,
  • Andrzej Majchrowski,
  • Jordi Arbiol,
  • Philippe Ghosez,
  • Gustau Catalan

摘要

Ferroelectric materials are characterized by a parallel arrangement of electric dipoles, but at the nanoscale they can present vortices and other non-trivial topological structures19 that combine small size and topological protection, rendering them functionally attractive1013. The driving force for the appearance of vortices in ferroelectrics is the need to minimize the depolarizing fields at interfaces35,14; by making the polarization rotate, depolarization fields vanish4,5,8,9. Antiferroelectrics, by contrast, are defined by an antiparallel arrangement of electric dipoles15. A priori, therefore, they lack the depolarization fields that drive the appearance of non-trivial topologies in ferroelectrics. At the atomic scale of the dipoles, however, we find that polar discontinuities can still happen, driving the appearance of topological singularities at ferroelastic domain walls.