Scholarlink

<p>Hydrogen peroxide is a clean and valuable oxidant that can be produced by photocatalysis under visible light. Developing efficient metal-free photocatalysts for this reaction is a key challenge. To address this challenge, we make two crystalline vinyl-linked covalent organic frameworks, ATP-COF-1 and ATP-COF-2, which contain triphenylamine and tetrazine units. ATP-COF-1 has a hydrogen peroxide production rate of 14,000 μmol g<sup>−1</sup>h<sup>−1</sup> with an apparent quantum yield of 23.05%, while ATP-COF-2 reaches 12,700 μmol g<sup>−1</sup>h<sup>−1</sup> and 20.38%. The higher activity originates from efficient photoinduced charge separation, driven by electron transfer between the electron-donating triphenylamine and electron-accepting tetrazine components. Ultrafast spectroscopy confirms prolonged excited-state lifetimes of 351.9 and 277.3 picoseconds, consistent with enhanced charge mobility. In this work, we show that integrating donor-acceptor building blocks within covalent organic frameworks enables efficient and stable visible-light-driven hydrogen peroxide production.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Charge transfer in triphenylamine–tetrazine covalent organic frameworks for solar-driven hydrogen peroxide production

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2025年11月29日

查看全文
  • Amin Zadehnazari,
  • Florian Auras,
  • Dimitrios Koumoulis,
  • Alireza Abbaspourrad

摘要

Hydrogen peroxide is a clean and valuable oxidant that can be produced by photocatalysis under visible light. Developing efficient metal-free photocatalysts for this reaction is a key challenge. To address this challenge, we make two crystalline vinyl-linked covalent organic frameworks, ATP-COF-1 and ATP-COF-2, which contain triphenylamine and tetrazine units. ATP-COF-1 has a hydrogen peroxide production rate of 14,000 μmol g−1h−1 with an apparent quantum yield of 23.05%, while ATP-COF-2 reaches 12,700 μmol g−1h−1 and 20.38%. The higher activity originates from efficient photoinduced charge separation, driven by electron transfer between the electron-donating triphenylamine and electron-accepting tetrazine components. Ultrafast spectroscopy confirms prolonged excited-state lifetimes of 351.9 and 277.3 picoseconds, consistent with enhanced charge mobility. In this work, we show that integrating donor-acceptor building blocks within covalent organic frameworks enables efficient and stable visible-light-driven hydrogen peroxide production.