Nematicity, spontaneous breaking of rotational symmetry, is a ubiquitous phenomenon in correlated quantum matter. Here we show a phase transition in high-quality ScV6Sn6 bilayer kagome metal at a temperature \({T}^{*}\) , occurring seven Kelvins below the charge density wave transition at \({T}_{{CDW}}\) , as indicated by thermodynamic, transport, and optical measurements. This emerging intermediate phase does not exhibit spontaneous time-reversal-symmetry breaking, as evidenced by zero-field Sagnac interferometry. However, it displays a strong, spontaneous in-plane anisotropy between \({T}^{*}\) and \({T}_{{CDW}}\) , revealed by transport and optical polarization rotation measurements. A pronounced depolarization effect detected by the Sagnac interferometer further confirms its nematic nature. Unlike AV3Sb5, this phase, alongside the recently discovered intra-unit cell nematic order at lower temperatures, presents a diverse landscape of nematicities at multiple length and temperature scales. Our findings highlight ScV6Sn6 as a prime candidate for realizing symmetry-breaking phases driven by charge density competition, kagome physics, and Van Hove singularities.
