Scholarlink

<p>Achieving high-stability thermoelectric materials with excellent average power factor and figure of merit is crucial for maximizing the output power density and conversion efficiency of thermoelectric devices. In this study, GaSb is added to PbSe as an n-type dopant to form stable solid solutions. Doping with GaSb flattens the conduction band and reduces the energy difference between the <i>Σ</i> and <i>L</i> conduction bands, thereby significantly improving the Seebeck coefficient. Herein, the Ga and Sb atoms co-occupy the vacant Pb sites, unlike in the case of traditional single-element doping, as is verified by density functional theory calculations. The resultant structural distortion is confirmed via transmission electron microscopy. This local structure distortion caused by GaSb doping reduces the lattice thermal conductivity. Consequently, the Pb<sub>0.99875</sub>(GaSb)<sub>0.00125</sub>Se sample exhibits a record-high average power factor of ~22.37 μW cm<sup>−1</sup> K<sup>−2</sup> and a high average figure of merit of ~0.94 in the temperature range of 300‒873 K. Furthermore, the introduction of interstitial Cu and discordant Zn atoms further reduces the lattice thermal conductivity. The Pb<sub>0.99875</sub>(GaSb)<sub>0.00125</sub>Zn<sub>0.01</sub>Se<sub>1.01</sub>-0.3%Cu sample exhibits a low lattice thermal conductivity of ~0.4 W m<sup>−1</sup> K<sup>−1</sup> at 873 K and a record-high average figure of merit of ~1.01 in the temperature range of 300‒873 K.</p>

错误：搜索内容不能为空，请输入英文关键词
错误：关键词超出字数限制，请精简
高级检索

Conduction band convergence and local structure distortion for superior thermoelectric performance of GaSb-doped n-type PbSe thermoelectrics

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2025年7月1日

查看全文
  • Jing Zhou,
  • Hong-Hua Cui,
  • Yukun Liu,
  • Hongwei Ming,
  • Yan Yu,
  • Vinayak P. Dravid,
  • Zhong-Zhen Luo,
  • Qingyu Yan,
  • Zhigang Zou,
  • Mercouri G. Kanatzidis

摘要

Achieving high-stability thermoelectric materials with excellent average power factor and figure of merit is crucial for maximizing the output power density and conversion efficiency of thermoelectric devices. In this study, GaSb is added to PbSe as an n-type dopant to form stable solid solutions. Doping with GaSb flattens the conduction band and reduces the energy difference between the Σ and L conduction bands, thereby significantly improving the Seebeck coefficient. Herein, the Ga and Sb atoms co-occupy the vacant Pb sites, unlike in the case of traditional single-element doping, as is verified by density functional theory calculations. The resultant structural distortion is confirmed via transmission electron microscopy. This local structure distortion caused by GaSb doping reduces the lattice thermal conductivity. Consequently, the Pb0.99875(GaSb)0.00125Se sample exhibits a record-high average power factor of ~22.37 μW cm−1 K−2 and a high average figure of merit of ~0.94 in the temperature range of 300‒873 K. Furthermore, the introduction of interstitial Cu and discordant Zn atoms further reduces the lattice thermal conductivity. The Pb0.99875(GaSb)0.00125Zn0.01Se1.01-0.3%Cu sample exhibits a low lattice thermal conductivity of ~0.4 W m−1 K−1 at 873 K and a record-high average figure of merit of ~1.01 in the temperature range of 300‒873 K.