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<p>Flexible perovskite solar cells (FPSCs) with high stability in moist air are required for their practical applications. However, the poor mechanical stability under high humidity air remains a critical challenge for flexible perovskite devices. Herein, inspired by the exceptional wet adhesion of mussels via dopamine groups, we propose a multidentate-cross-linking strategy, which combine multibranched structure and adequate dopamine anchor sites in three-dimensional hyperbranched polymer to directly chelate perovskite materials in multiple directions, therefore construct a vertical scaffold across the bulk of perovskite films from the bottom to the top interfaces, intimately bind to the perovskite grains and substrates with a strong adhesion ability, and enhance mechanical durability under high humidity. Consequently, the modified rigid PSCs achieve superior PCE up to 25.92%, while flexible PSCs exhibit a PCE of 24.43% and maintain 94.1% of initial PCE after 10,000 bending cycles with a bending radius of 3 mm under exposed to 65% humidity.</p>

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Boosting mechanical durability under high humidity by bioinspired multisite polymer for high-efficiency flexible perovskite solar cells

  • 期刊论文

  • 出版模式：

    开放获取

  • 发表日期：

    2025年2月19日

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  • Zhihao Li,
  • Chunmei Jia,
  • Zhi Wan,
  • Junchao Cao,
  • Jishan Shi,
  • Jiayi Xue,
  • Xirui Liu,
  • Hongzhuo Wu,
  • Chuanxiao Xiao,
  • Can Li,
  • Meng Li,
  • Chao Zhang,
  • Zhen Li

摘要

Flexible perovskite solar cells (FPSCs) with high stability in moist air are required for their practical applications. However, the poor mechanical stability under high humidity air remains a critical challenge for flexible perovskite devices. Herein, inspired by the exceptional wet adhesion of mussels via dopamine groups, we propose a multidentate-cross-linking strategy, which combine multibranched structure and adequate dopamine anchor sites in three-dimensional hyperbranched polymer to directly chelate perovskite materials in multiple directions, therefore construct a vertical scaffold across the bulk of perovskite films from the bottom to the top interfaces, intimately bind to the perovskite grains and substrates with a strong adhesion ability, and enhance mechanical durability under high humidity. Consequently, the modified rigid PSCs achieve superior PCE up to 25.92%, while flexible PSCs exhibit a PCE of 24.43% and maintain 94.1% of initial PCE after 10,000 bending cycles with a bending radius of 3 mm under exposed to 65% humidity.