<p>Electric field-induced splay of molecular orientation, called the Fréedericksz transition, is a fundamental electro-optic phenomenon in nonpolar nematic liquid crystals. In a ferroelectric nematic N<sub>F</sub> with a spontaneous electric polarization <InlineEquation ID="IEq1"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41467_2025_55827_Article_IEq1.gif" Format="GIF" Height="14" Rendition="HTML" Resolution="72" Type="Linedraw" Width="15" /> </InlineMediaObject> <EquationSource Format="TEX">\({{\bf{P}}}\)</EquationSource> <EquationSource Format="MATHML"><math> <mi mathvariant="bold">P</mi> </math></EquationSource> </InlineEquation>, the splay is suppressed since it produces bound electric charges. Here, we demonstrate that an alternating current (ac) electric field causes three patterns of N<sub>F</sub> polarization. At low voltages, <InlineEquation ID="IEq2"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41467_2025_55827_Article_IEq2.gif" Format="GIF" Height="14" Rendition="HTML" Resolution="72" Type="Linedraw" Width="15" /> </InlineMediaObject> <EquationSource Format="TEX">\({{\bf{P}}}\)</EquationSource> <EquationSource Format="MATHML"><math> <mi mathvariant="bold">P</mi> </math></EquationSource> </InlineEquation> oscillates around the field-free orientation with no stationary deformations. As the voltage increases, the polarization acquires stationary distortions, first splay and twist in a stripe pattern and then splay and bend in a square lattice of +1 and -1 defects. In all patterns, <InlineEquation ID="IEq3"> <InlineMediaObject> <ImageObject Color="BlackWhite" FileRef="41467_2025_55827_Article_IEq3.gif" Format="GIF" Height="14" Rendition="HTML" Resolution="72" Type="Linedraw" Width="15" /> </InlineMediaObject> <EquationSource Format="TEX">\({{\bf{P}}}\)</EquationSource> <EquationSource Format="MATHML"><math> <mi mathvariant="bold">P</mi> </math></EquationSource> </InlineEquation> oscillates around the stationary orientations. The stationary bound charge is reduced by a geometrical “splay cancellation” mechanism that does not require free ions: the charge created by splay in one plane is reduced by splay of an opposite sign in the orthogonal plane.</p>

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Periodic splay Fréedericksz transitions in a ferroelectric nematic

  • Bijaya Basnet,
  • Sathyanarayana Paladugu,
  • Oleksandr Kurochkin,
  • Oleksandr Buluy,
  • Natalie Aryasova,
  • Vassili G. Nazarenko,
  • Sergij V. Shiyanovskii,
  • Oleg D. Lavrentovich

摘要

Electric field-induced splay of molecular orientation, called the Fréedericksz transition, is a fundamental electro-optic phenomenon in nonpolar nematic liquid crystals. In a ferroelectric nematic NF with a spontaneous electric polarization \({{\bf{P}}}\) P , the splay is suppressed since it produces bound electric charges. Here, we demonstrate that an alternating current (ac) electric field causes three patterns of NF polarization. At low voltages, \({{\bf{P}}}\) P oscillates around the field-free orientation with no stationary deformations. As the voltage increases, the polarization acquires stationary distortions, first splay and twist in a stripe pattern and then splay and bend in a square lattice of +1 and -1 defects. In all patterns, \({{\bf{P}}}\) P oscillates around the stationary orientations. The stationary bound charge is reduced by a geometrical “splay cancellation” mechanism that does not require free ions: the charge created by splay in one plane is reduced by splay of an opposite sign in the orthogonal plane.