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<p>Perovskite quantum dots (PQDs) show promise in light-emitting diodes (LEDs). However, near-infrared (NIR) LEDs employing PQDs exhibit inferior external quantum efficiency related to the PQD emitting in the visible range. One fundamental issue arises from the PQDs dynamic surface: the ligand loss and ions migration to the interfacial sites serve as quenching centers, resulting in trap-assisted recombination and carrier loss. In this work, we developed a chemical treatment strategy to eliminate the interface quenching sites and achieve high carrier utilization. We employ a bidentate and liquid agent (Formamidine thiocyanate, FASCN) with tight binding to suppress the ligand loss and the formation of interfacial quenching sites: the FASCN-treated films exhibit fourfold higher binding energy than the original oleate ligands. Furthermore, the short ligands (carbon chain &lt;3) enable the treated films to show eightfold higher conductivity; and the liquid characteristics of FASCN avoid the use of high polar solvents and guarantee better passivation. The high conductivity ensures efficient charge transportation, enabling PQD-based NIR-LEDs to have a record-low voltage of 1.6 V at 776 nm. Furthermore, the champion EQE of the treated LEDs is ~23%: this is twofold higher than the control, and represents the highest among reported PQD-based NIR-LEDs.</p>

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Liquid bidentate ligand for full ligand coverage towards efficient near-infrared perovskite quantum dot LEDs

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年1月7日

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  • Zong-Shuo Liu,
  • Ye Wang,
  • Feng Zhao,
  • Hua-Hui Li,
  • Wei-Zhi Liu,
  • Wan-Shan Shen,
  • Hong-Wei Duan,
  • Ya-Kun Wang,
  • Liang-Sheng Liao

摘要

Perovskite quantum dots (PQDs) show promise in light-emitting diodes (LEDs). However, near-infrared (NIR) LEDs employing PQDs exhibit inferior external quantum efficiency related to the PQD emitting in the visible range. One fundamental issue arises from the PQDs dynamic surface: the ligand loss and ions migration to the interfacial sites serve as quenching centers, resulting in trap-assisted recombination and carrier loss. In this work, we developed a chemical treatment strategy to eliminate the interface quenching sites and achieve high carrier utilization. We employ a bidentate and liquid agent (Formamidine thiocyanate, FASCN) with tight binding to suppress the ligand loss and the formation of interfacial quenching sites: the FASCN-treated films exhibit fourfold higher binding energy than the original oleate ligands. Furthermore, the short ligands (carbon chain <3) enable the treated films to show eightfold higher conductivity; and the liquid characteristics of FASCN avoid the use of high polar solvents and guarantee better passivation. The high conductivity ensures efficient charge transportation, enabling PQD-based NIR-LEDs to have a record-low voltage of 1.6 V at 776 nm. Furthermore, the champion EQE of the treated LEDs is ~23%: this is twofold higher than the control, and represents the highest among reported PQD-based NIR-LEDs.