Let \(\mathcal {M}_{n}\) be the set of \(n\times n\) complex matrices. Complete descriptions are given of the maps on \(\mathcal {M}_{n}\) leaving invariant the numerical range of different kind of binary operations on matrices such as the skew product, the skew Lie product, the skew Jordan product and the skew semi-triple product, with no surjectivity assumption on them.