Comparative Evaluation of Gravity–CIL and Flotation–Pretreatment–CIL Routes for the Recovery of Gold from Refractory Sulphide Ore
摘要
The recovery of gold from refractory sulphide ores remains a major challenge due to the encapsulation of gold within sulphide matrices and the presence of preg-robbing carbonaceous matter. This study investigates and compares two integrated processing routes for the recovery of gold from refractory sulphide ore from the Tri-K deposit (Guinea). Two representative composite samples, KLK and KD, were tested through laboratory-scale gravity separation followed by cyanidation (gravity–CIL route) and flotation followed by oxidative pretreatment and intensive cyanidation (flotation–pretreatment–CIL route). Diagnostic leaching and SEM-EDX analyses revealed that gold occurs mainly as electrum (Au–Ag) finely disseminated within pyrite and arsenopyrite. Gravity concentration-CIL route yielded modest recoveries. Incorporation of flotation followed by oxidative pretreatments improved gold extraction by 11% for KLK and 5% for KD, with oxidation achieving up to 87% sulphur and arsenic removal. The results demonstrate that controlled oxidation coupled with fine grinding significantly enhances gold accessibility and cyanidation kinetics. These findings provide a metallurgical basis for selecting optimal pretreatment strategies for the treatment of refractory sulphide ores of Tri-K deposit.