<p>The main objective of this research work is to investigate the structural, topological, dielectric, and electrical characteristics of powellite calcium molybdate with suitable application. The investigation of X-ray diffraction (XRD) pattern shows tetragonal symmetry having lattice parameters: a = b = 5.2257 Å, c = 11.4303 Å, cell volume: 312.14 (Å)³ and centerosymmetric space group I41/a. The pair distribution function (PDF) spectrum reveals the atomic orientations of the tetragonal symmetry. The avg. crystallite size (244.66 nm) and micro-lattice strain (0.0017) are investigated using the Williamson-Hall plot. The exploration of well-defined grains, grain boundaries, purity, compactness, and topographic roughness (ISO25178) of CaMoO₄ has been confirmed by scanning electron microscope with energy dispersive X-ray (EDX) spectra. The relaxation phenomena, Maxwell–Wagner dielectric dispersion, and transport mechanisms are investigated by analyzing impedance, dielectric, and conduction spectra across a wide spectrum of frequencies and temperatures. This comprehensive approach allows for a thorough understanding of the electrical behavior of the sample. The scaling behavior of modulus spectra supports the non-Debye relaxation mechanism. The temperature-dependent resistance behavior confirms the prepared material can also be used for the NTC thermistor. The varistor constants β₁, β₂, and β₃ are 1.267, 2.046, and 11.609, signifying the occurrence of non-Ohmic mechanism, which is also appropriate for electronic devices.</p>