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<p>In this study, we created complex structures using a mix of ligands that included acesulfame, a pure ligand, and acesulfame-1,10-phenanthroline ligands with aluminum (Al) and indium (In) metal cations, which belong to group 3A and have a +3 charge, and we looked into their structures. The acesulfame molecule is a valuable ligand in coordination chemistry because of the large number of electron donating groups it contains. The chemical makeup of the complexes was examined through elemental analysis, their structural features were analyzed using FTIR, solid-state UV-GB, and GC-MS spectroscopy, and their thermal properties were assessed with TGA/DTA/DrTGA methods. The chemical compositions of the synthesized complexes were studied by elemental analysis, their structural properties were studied by FTIR, solid-state UV-GB, and GC-MS spectroscopy, and their thermal behavior was studied by TGA/DTA/DrTGA analysis methods.</p>

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Novel Homoleptic and Heteroleptic Complexes of Al³+ and In³+ Containing Acesulfame and 1,10-Phenanthroline Ligands

  • 期刊论文

  • 发表日期：

    2025年11月6日

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  • Halide Kundakçı,
  • Melda Bolat,
  • Dursun Ali Köse

摘要

In this study, we created complex structures using a mix of ligands that included acesulfame, a pure ligand, and acesulfame-1,10-phenanthroline ligands with aluminum (Al) and indium (In) metal cations, which belong to group 3A and have a +3 charge, and we looked into their structures. The acesulfame molecule is a valuable ligand in coordination chemistry because of the large number of electron donating groups it contains. The chemical makeup of the complexes was examined through elemental analysis, their structural features were analyzed using FTIR, solid-state UV-GB, and GC-MS spectroscopy, and their thermal properties were assessed with TGA/DTA/DrTGA methods. The chemical compositions of the synthesized complexes were studied by elemental analysis, their structural properties were studied by FTIR, solid-state UV-GB, and GC-MS spectroscopy, and their thermal behavior was studied by TGA/DTA/DrTGA analysis methods.