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Physicochemical characteristics of DyFeO3 perovskite nanoparticles synthesized by a simple co-precipitation method at room temperature

  • Nguyen Thi Kim Chung,
  • Tran Dinh Trinh,
  • Valentina Olegovna Mittova,
  • Elena Viktorovna Tomina,
  • Irina Yakovlevna Mittova,
  • Vu Thi Ngoc Anh,
  • Nguyen Anh Tien,
  • Bui Thi Hoa,
  • Bui Xuan Vuong

摘要

DyFeO3 nanoparticles were successfully prepared by a simple co-precipitation method at room temperature using 0.2% ammonia solution as the precipitating agent. The characteristics of DyFeO3 nanoparticles were studied by PXRD, FTIR, EDX-mapping, TEM, DRS, and VSM methods. The results revealed a homogeneous distribution of the main elements on the samples' surfaces, with morphology consisting of isometric and highly agglomerated nanoparticles. TEM analysis indicated a particle size range of 70–100 nm for DyFeO3 materials. After calcination at 750, 850, and 950 °C for 1 h, the obtained DyFeO3 nanoparticles exhibited coercivities (Hc) of 250.03–497.02 Oe, remanent magnetizations (Mr) of 0.2–0.79 emu·g−1, net magnetizations (Mn) of 2.96–3.88 emu·g−1, and optical energy gap (Eg) of 1.75–1.85 eV. The synthesized DyFeO3 nanomaterials has strong optical absorption in both ultraviolet and visible regions, suggesting their potential as catalysts for the decomposition of toxic organic compounds under solar irradiation.