<p>The high-temperature corrosion behaviors of an as-rolled Fe–17.4Cr–12.4Ni–2.63Mo–1.57Mn–0.044C (in&#xa0;wt.%) austenitic stainless steel in nuclear-grade helium environments containing with 10, 100 and 1000 magnification impurity tolerance concentrations at 550&#xa0;°C were investigated and compared. Based on the quantitative relationship between mass gain and corrosion time, the high-temperature corrosion kinetics curves of the alloy in different helium environments were determined. The results demonstrated that for different samples, their mass gains exhibited a parabolic increase over the corrosion time. Raman spectroscopy and GIXRD analyses revealed that the high-temperature corrosion mechanisms of different samples are similar and the formed surface oxide layers were primarily composed of Fe<sub>2</sub>O<sub>3</sub>, Cr<sub>2</sub>O<sub>3</sub>, Fe<sub>3</sub>O<sub>4</sub> and NiFe<sub>2</sub>O<sub>4</sub>. Under the equivalent corrosion damage and mass gain conditions in helium containing with 10, 100 and 1000 magnification impurity tolerance concentrations, the corresponding corrosion time required to achieve a mass gain of 0.5&#xa0;mg/cm<sup>2</sup> were determined to be 200, 600 and 1000&#xa0;h, respectively. Based on the principle of same damage mechanism and equal damage degree, an acceleration testing method was proposed and the corresponding empirical formulas were established for evaluating the long-term high-temperature corrosion extent of austenitic stainless steels in nuclear-grade helium environments.</p>

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Corrosion behavior of as-rolled Fe–17.4Cr–12.4Ni–2.63Mo–1.57Mn–0.044C (in wt.%) stainless steel in high-temperature impurity gases

  • Xiang-Bo Xu,
  • Dao-Kui Xu,
  • Shuo Wang,
  • Sheng-Hu Chen

摘要

The high-temperature corrosion behaviors of an as-rolled Fe–17.4Cr–12.4Ni–2.63Mo–1.57Mn–0.044C (in wt.%) austenitic stainless steel in nuclear-grade helium environments containing with 10, 100 and 1000 magnification impurity tolerance concentrations at 550 °C were investigated and compared. Based on the quantitative relationship between mass gain and corrosion time, the high-temperature corrosion kinetics curves of the alloy in different helium environments were determined. The results demonstrated that for different samples, their mass gains exhibited a parabolic increase over the corrosion time. Raman spectroscopy and GIXRD analyses revealed that the high-temperature corrosion mechanisms of different samples are similar and the formed surface oxide layers were primarily composed of Fe2O3, Cr2O3, Fe3O4 and NiFe2O4. Under the equivalent corrosion damage and mass gain conditions in helium containing with 10, 100 and 1000 magnification impurity tolerance concentrations, the corresponding corrosion time required to achieve a mass gain of 0.5 mg/cm2 were determined to be 200, 600 and 1000 h, respectively. Based on the principle of same damage mechanism and equal damage degree, an acceleration testing method was proposed and the corresponding empirical formulas were established for evaluating the long-term high-temperature corrosion extent of austenitic stainless steels in nuclear-grade helium environments.