Effect of SiC morphology on oxidation behaviour of ZrB2-SiC composite
摘要
Addition of short carbon fibre (Cf) in ZrB2-SiC composite promotes the formation of slender SiC grains network which has large ZrB2/SiC interfacial area and gets fully oxidized even at lower temperature (~1300°C) and shorter exposure time (~30s) at the initial stage of oxidation. Lower temperature oxidation renders uniform ZrB2 oxidation also. Thinnest SiC grains are fully oxidized in the beginning of oxidation since SiC oxidation starts from the ZrB2/SiC interfacial area and move progressively towards the core region. This leads to formation of SiO2 protective outer scale for Cf-added composite at the outset of oxidation at l.ower temperature and consequent mitigation of active SiC oxidation and internal oxidation at higher temperature (1625°C). On the other hand, the extent of uniform ZrB2-oxidation is found to be more than SiC-oxidation for the coarser SiC grain bearing pristine composite (without Cf) at lower temperature (~1300°C). During lower temperature oxidation of pristine ZrB2-SiC composite, uniform oxidation of ZrB2 and partial oxidation (outer-SiO2+inner-SiC) of coarser SiC grains occur which lead to formation of non-protective outer SiO2 layer. Above 1500 °C, irrespective of its grain size SiC becomes more prone to oxidation than the ZrB2 phase because of active SiC-oxidation. Cf addition to ZrB2-SiC composite renders suppression of active SiC-oxidation by increasing CO partial pressure beneath the protective outer SiO2 scale and consequently reduces SiC depleted region. However, pristine ZrB2-SiC composite with coarser SiC grains shows larger SiC depleted region due to active SiC-oxidation and heavy internal oxidation at higher temperature (1625°C) beneath the non-protective outer SiO2 scale.