<p>Transition metal oxide electrocatalysts have gained attention for their potential in eco-friendly electrochemical applications, due to their affordability, durability, structural adaptability, and customizable catalytic activity. This study integrates 5d transition metal oxide nanoparticles MoO<sub>3</sub> with a porous FeTe array on nickel foam to form the MoO<sub>3</sub>@FeTe/NF porous nanosphere array. This structure achieves low overpotentials of 42 mV for the hydrogen evolution reaction (HER) and 222 mV for the oxygen evolution reaction (OER) at 10&#xa0;mA cm<sup>− 2</sup>, with OER and HER Tafel slopes of 108 mV dec<sup>− 1</sup> and 66 mV dec<sup>− 1</sup>, respectively, demonstrating stability over 25&#xa0;h during HER testing, and 80&#xa0;h for OER. The MoO<sub>3</sub>@FeTe/NF nanocatalyst also reaches a current density of 10&#xa0;mA cm<sup>− 2</sup> with a cell voltage of 1.5&#xa0;V. This research presents an effective method for creating cost-effective electrocatalysts for water-splitting applications.</p>

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Facile synthesis of molybdenum trioxide supported nanospheres Iron telluride for highly efficient electrocatalytic oxygen and hydrogen production

  • Asma A. Alothman,
  • Jafar Hussain Shah,
  • Abdul Ghafoor Abid,
  • Asmaa Benettayeb,
  • Mika Sillanpaa

摘要

Transition metal oxide electrocatalysts have gained attention for their potential in eco-friendly electrochemical applications, due to their affordability, durability, structural adaptability, and customizable catalytic activity. This study integrates 5d transition metal oxide nanoparticles MoO3 with a porous FeTe array on nickel foam to form the MoO3@FeTe/NF porous nanosphere array. This structure achieves low overpotentials of 42 mV for the hydrogen evolution reaction (HER) and 222 mV for the oxygen evolution reaction (OER) at 10 mA cm− 2, with OER and HER Tafel slopes of 108 mV dec− 1 and 66 mV dec− 1, respectively, demonstrating stability over 25 h during HER testing, and 80 h for OER. The MoO3@FeTe/NF nanocatalyst also reaches a current density of 10 mA cm− 2 with a cell voltage of 1.5 V. This research presents an effective method for creating cost-effective electrocatalysts for water-splitting applications.