Fabrication of Novel SrSnO3–NrGO Composite for Ciprofloxacin Removal and Antibacterial Studies
摘要
This study presents the synthesis of a novel SrSnO₃/NrGO composite using a sol–gel and hydrothermal approach and evaluates its dual functionality for ciprofloxacin (CIP) adsorption and antibacterial activity. The integration of NrGO into the SrSnO₃ matrix significantly enhanced structural and surface characteristics, as confirmed by XRD, FTIR, SEM, and BET analyses. Notably, the specific surface area increased from 54.46 to 130.7 m2/g, while XRD revealed a reduction in the SrSnO₃ (200) peak intensity, indicating strong interfacial interaction with NrGO. FTIR verified successful nitrogen incorporation into the GO lattice, and SEM imaging demonstrated uniform dispersion of SrSnO₃ cuboids across the NrGO sheets. Optimised adsorption conditions (pH 7 ± 0.2, 0.4 g/L dosage, 120 min contact time, and 10 mg/L CIP concentration) yielded a maximum monolayer adsorption capacity of 58.82 mg/g, fitting well with the Langmuir isotherm and pseudo-second-order kinetics. Thermodynamic parameters confirmed that the process is favourable, spontaneous, and exothermic. Beyond adsorption, the composite exhibited strong antibacterial activity, with MIC values ranging from 62.5 to 250 μg/mL against both Gram-positive (Streptococcus pyogenes, Streptococcus mutans) and Gram-negative (Salmonella typhi, Vibrio cholera) strains. Overall, unlike most SrSnO₃-based composites that have primarily been explored as photocatalysts, the SrSnO₃/NrGO composite developed in this study exhibits a distinct dual functionality, demonstrating both superior adsorption capacity for CIP and strong antibacterial activity. This enhanced performance, driven by the NrGO-mediated increase in surface area and active sites, highlights the composite’s novelty and its promising potential as a multifunctional material for integrated wastewater purification and antibacterial applications.
Graphical Abstract